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Merck
CN

437867

溴化铜(II)

99.999% trace metals basis

别名:

溴化铜

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线性分子式:
CuBr2
化学文摘社编号:
7789-45-9
分子量:
223.35
NACRES:
NA.23
PubChem Substance ID:
24867403
UNSPSC Code:
12352302
EC Number:
232-167-2
MDL number:
MFCD00010970
Assay:
99.999% trace metals basis
Form:
solid

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产品名称

溴化铜(II), 99.999% trace metals basis

InChI key

QTMDXZNDVAMKGV-UHFFFAOYSA-L

InChI

1S/2BrH.Cu/h2*1H;/q;;+2/p-2

SMILES string

Br[Cu]Br

assay

99.999% trace metals basis

form

solid

reaction suitability

core: copper

impurities

≤15.0 ppm Trace Metal Analysis

mp

498 °C (lit.)

density

4.77 g/mL at 25 °C (lit.)

Quality Level

100

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相关类别

Application

溴化铜在有机反应中可用作催化剂和溴化剂。铜催化的乙炔封端的聚乙二醇甲基醚甲基丙烯酸酯（PEGMEMA）链的生物素化已被研究。乙腈中的二溴化铜可在缩醛向双（甲氧基苯基）甲基（BMPM）醚的相互转化中充当催化剂。它已作为一种催化剂用于α-羰基的分子内脱羧官能化以生成用于合成呋喃[3,2-c]香豆素的C(sp(3))-O键。聚（3,4-乙撑二氧噻吩）：聚（苯乙烯磺酸盐）（PEDOT:PSS）已被报道在掺杂CuBr2后可充当聚合物太阳能电池（PSC）中的空穴传输层（HTL）。这种掺杂增加了电导率，从而提高了PSC的器件功率转换效率。

General description

溴化铜是一种单斜晶体材料。它易溶于水、乙醇和丙酮。它可通过使用氢溴酸中和铜的氧化物、碳酸盐或氢氧化物来进行合成。另一种合成技术是通过用溴水或溴的乙醇溶液来对铜进行氧化。

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000462122
0000462122
0000435279
0000435279
0000306909

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Copper(II) bromide as an efficient catalyst for acetal to bisarylmethyl ether interconversion
Mezaache R, et al.
Tetrahedron Letters, 55(52), 7167-7171 (2014)
Richardson HW
Handbook of Copper Compounds and Applications null
Copper(ii) bromide-catalyzed intramolecular decarboxylative functionalization to form a C(sp(3))-O bond for the synthesis of furo[3,2-c]coumarins.
Zhang WL, et al.
Organic & Biomolecular Chemistry, 13(12), 3602-3609 null
Zhiqiang Zhao et al.
ACS applied materials & interfaces, 7(3), 1439-1448 (2014-12-24)
Copper(II) bromide (CuBr2) salt has been applied to dope poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the hole transport layer (HTL) in polymer solar cells (PSCs), improving dramatically the conductivity of PEDOT:PSS film and consequently the device power conversion efficiency (PCE). Under the
Gavin T Knight et al.
Journal of visualized experiments : JoVE, 92(92), e52186-e52186 (2014-11-20)
In tissue engineering, it is desirable to exhibit spatial control of tissue morphology and cell fate in culture on the micron scale. Culture substrates presenting grafted poly(ethylene glycol) (PEG) brushes can be used to achieve this task by creating microscale
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