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438839

1-(苯基磺酰基)吡咯

Name: 1-(苯基磺酰基)吡咯
Brand: ALDRICH

98%

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关于此项目

经验公式（希尔记法）:

C₁₀H₉NO₂S

化学文摘社编号:

16851-82-4

分子量:

207.25

NACRES:

NA.22

PubChem Substance ID:

24867474

UNSPSC Code:

12352100

MDL number:

MFCD00067739

Assay:

98%

Form:

solid

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属性

assay

98%

form

solid

mp

88-91 °C (lit.)

SMILES string

O=S(=O)(c1ccccc1)n2cccc2

InChI

1S/C10H9NO2S/c12-14(13,11-8-4-5-9-11)10-6-2-1-3-7-10/h1-9H

InChI key

PPPXRIUHKCOOMU-UHFFFAOYSA-N

说明

General description

1-(Phenylsulfonyl)pyrrole is a heterocyclic building block. 1-(Phenylsulfonyl) group serves as N-blocking and directing group in various organic syntheses.

Application

1-(Phenylsulfonyl)pyrrole (1-phenylsulfonyl-1H-pyrrole) may be used in the synthesis of 1-(phenylsulfonyl)pyrrole-2-boronic acid, via lithiation of 1-(phenylsulfonyl)-pyrrole. It may be used for the synthesis of 1-phenylsulfonyl-1H-pyrrole-3-sulfonyl chloride derivatives, which affords sulfonamide derivatives by reaction with nitrogen nucleophiles.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Efficient sulfonation of 1-phenylsulfonyl-1H-pyrroles and 1-phenylsulfonyl-1H-indoles using chlorosulfonic acid in acetonitrile.

Janosik T, et al.

Tetrahedron, 62(8), 1669-1707 (2006)

Pyrrole chemistry. XXVIII. Substitution reactions of 1-(phenylsulfonyl) pyrrole and some derivatives.

Anderson HJ, et al.

Canadian Journal of Chemistry, 63(4), 896-902 (1985)

Synthesis of 2-Aryl-1-(phenylsulfonyl) pyrroles.

Grieb JG and Ketcha DM.

Synthetic Communications, 25(14), 2145-2153 (1995)

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货号	GTIN
438839-5G	04061833323281