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经验公式(希尔记法):
C10H18O
化学文摘社编号:
分子量:
154.25
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4659691
Assay:
99%
Form:
liquid
InChI
1S/C10H18O/c1-7(2)9-5-4-8(3)6-10(9)11/h8-11H,1,4-6H2,2-3H3/t8-,9+,10-/m0/s1
SMILES string
C[C@H]1CC[C@@H]([C@@H](O)C1)C(C)=C
InChI key
ZYTMANIQRDEHIO-AEJSXWLSSA-N
assay
99%
form
liquid
optical activity
[α]20/D +22°, neat
refractive index
n20/D 1.469 (lit.)
bp
91 °C/12 mmHg (lit.)
density
0.912 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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General description
异蒲勒醇是一种单萜醇,通常存在于各种植物精油中。它被广泛用作化妆品、洗发水和香皂中的香精成分。异蒲勒醇也是(−)-薄荷醇合成中的关键中间体。
Application
(+)-异蒲勒醇可用作合成以下物质的起始原料:
- 天然产物(−)-异胡薄荷烯酮 (isopiperitenone)。
- 通过与苯甲醛反应制备医学上重要的八氢-2H-苯并吡喃-4-醇衍生物
- 抗结核二萜类化合物12-epi-ileabethoxazole。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
172.4 °F - closed cup
flash_point_c
78 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Chemoenzymatic synthesis of the intermediates in the peppermint monoterpenoid biosynthetic pathway
Cheallaigh AN, et al.
Journal of Natural Products, 81(7), 1546-1552 (2018)
Fragrance material review on isopulegol
Bhatia SP, et al.
Food And Chemical Toxicology, 46(11), S185-S189 (2008)
Central nervous system activity of acute administration of isopulegol in mice
Silva MIG, et al.
Pharmacology, Biochemistry, and Behavior, 88(2), 141-147 (2007)
One-step, stereoselective synthesis of octahydrochromanes via the Prins reaction and their cannabinoid activities
Slater S, et al.
Tetrahedron Letters, 59(9), 807-810 (2018)
Total Synthesis of Ileabethoxazole, Pseudopteroxazole, and seco-Pseudopteroxazole
Yang M, et al.
Angewandte Chemie (International ed. in English), 55(8), 2851-2855 (2016)
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