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440442

O-(三甲基硅基)羟胺

technical grade, 90%

别名:

氨氧基三甲基硅烷

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关于此项目

线性分子式:
(CH3)3SiONH2
化学文摘社编号:
22737-36-6
分子量:
105.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24867596
MDL number:
MFCD00010872
Beilstein/REAXYS Number:
2035893
Assay:
90%
Form:
liquid
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grade

technical grade

assay

90%

form

liquid

refractive index

n20/D 1.405 (lit.)

bp

98-100 °C (lit.)

density

0.86 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)ON

InChI

1S/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3

InChI key

AEKHNNJSMVVESS-UHFFFAOYSA-N

General description

O-(Trimethylsilyl)hydroxylamine is an O-substituted hydroxylamine. It is formed as an intermediate during the trimethylsilyl chloride catalyzed synthesis of α-branched amines.

Application

O-(Trimethylsilyl)hydroxylamine may be used for the preparation of O-trimethylsilyl oxime ethers.

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

hcodes

H225,H314

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

53.6 °F - closed cup

flash_point_c

12 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number
MKCM4187
MKCH2099
MKCC9672
MKBV5927V
MKBP0413V

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Chemoselective addition of organometallics to oxime ethers.
Tavakol H,et al.
Journal of Organometallic Chemistry, 692(10), 1924-1927 (2007)
Ying Fu et al.
Organic & biomolecular chemistry, 10(38), 7669-7672 (2012-08-14)
A general procedure for the nucleophilic addition of organozinc halides with nitrones in the presence of trimethylsilyl chloride has been developed. Trimethylsilyl chloride was found to be both an indispensable reaction promoter and a ready hydroxylamine protective agent in these

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货号GTIN
440442-1G04061836826932
440442-5G04061836826949