440442
O-(三甲基硅基)羟胺
technical grade, 90%
别名:
氨氧基三甲基硅烷
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线性分子式:
(CH3)3SiONH2
化学文摘社编号:
分子量:
105.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2035893
产品名称
O-(三甲基硅基)羟胺, technical grade, 90%
InChI
1S/C3H11NOSi/c1-6(2,3)5-4/h4H2,1-3H3
SMILES string
C[Si](C)(C)ON
InChI key
AEKHNNJSMVVESS-UHFFFAOYSA-N
grade
technical grade
assay
90%
form
liquid
refractive index
n20/D 1.405 (lit.)
bp
98-100 °C (lit.)
density
0.86 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
O-(Trimethylsilyl)hydroxylamine may be used for the preparation of O-trimethylsilyl oxime ethers.
General description
O-(Trimethylsilyl)hydroxylamine is an O-substituted hydroxylamine. It is formed as an intermediate during the trimethylsilyl chloride catalyzed synthesis of α-branched amines.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
53.6 °F - closed cup
flash_point_c
12 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Ying Fu et al.
Organic & biomolecular chemistry, 10(38), 7669-7672 (2012-08-14)
A general procedure for the nucleophilic addition of organozinc halides with nitrones in the presence of trimethylsilyl chloride has been developed. Trimethylsilyl chloride was found to be both an indispensable reaction promoter and a ready hydroxylamine protective agent in these
Chemoselective addition of organometallics to oxime ethers.
Tavakol H,et al.
Journal of Organometallic Chemistry, 692(10), 1924-1927 (2007)
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