2,2-偶氮二(2-甲基丙基咪) 二盐酸盐

Name: 2,2-偶氮二(2-甲基丙基咪) 二盐酸盐
Brand: ALDRICH

powder or granules, 97%

别名:

2,2′-偶氮二异丁基脒二盐酸盐, AAPH

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关于此项目

线性分子式:

[=NC(CH₃)₂C(=NH)NH₂]₂·2HCl

化学文摘社编号:

2997-92-4

分子量:

271.19

UNSPSC Code:

12162002

NACRES:

NA.23

PubChem Substance ID:

24867630

EC Number:

221-070-0

Beilstein/REAXYS Number:

3718854

MDL number:

MFCD00142725

主要文件

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产品名称

2,2-偶氮二(2-甲基丙基咪) 二盐酸盐, powder or granules, 97%

InChI key

LXEKPEMOWBOYRF-QDBORUFSSA-N

InChI

1S/C8H18N6.2ClH/c1-7(2,5(9)10)13-14-8(3,4)6(11)12;;/h1-4H3,(H3,9,10)(H3,11,12);2*1H/b14-13+;;

SMILES string

Cl.Cl.CC(C)(\N=N\C(C)(C)C(N)=N)C(N)=N

assay

97%

form

powder or granules

t_1/2

10 hr(56 °C)

mp

175-177 °C (lit.)

solubility

acetone, dioxane, methanol, ethanol, DMSO and water: soluble

Quality Level

200

Application

自由基引发剂。
丙烯酸、乙烯基、烯丙基单体聚合反应的引发剂。

Features and Benefits

可发生一级分解形成阳离子型自由基。在紫外光照射下分解。与阳离子表面活性剂相容。分解速率取决于 pH 值。

pictograms

GHS02,GHS07,GHS09

signalword

Danger

hcodes

H251,H302,H317,H319,H410

pcodes

P235 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Self-heat. 1 - Skin Sens. 1

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Characteristics of the spin-trapping reaction of a free radical derived from AAPH: further development of the ORAC-ESR assay.

A Nakajima et al.

Analytical and bioanalytical chemistry, 403(7), 1961-1970 (2012-05-01)

The characteristics of the spin-trapping reaction in the oxygen radical absorbance capacity (ORAC)-electron spin resonance (ESR) assay were examined, focusing on the kind of spin traps. 2,2-Azobis(2-amidinopropane) dihydrochloride (AAPH) was used as a free radical initiator. The spin adducts of

Purification and determination of two novel antioxidant peptides from flounder fish (Paralichthys olivaceus) using digestive proteases.

Ju-Young Ko et al.

Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 52, 113-120 (2012-11-14)

We investigated the effects of bioactive-peptides from hydrolysates of flounder fish muscle (FFM) on antioxidant activity. The hydrolysates were prepared by enzymatic reactions of FFM using eight commercial proteases such as papain, pepsin, trypsin, neutrase, alcalase, kojizyme, protamex, and α-chymotrypsin.

Phospholipase A₂: the key to reversing long-term memory impairment in a gastropod model of aging.

Shawn N Watson et al.

Neurobiology of aging, 34(2), 610-620 (2012-03-31)

Memory failure associated with changes in neuronal circuit functions rather than cell death is a common feature of normal aging in diverse animal species. The (neuro)biological foundations of this phenomenon are not well understood although oxidative stress, particularly in the

Intramolecular hydrogen transfer reactions of thiyl radicals from glutathione: formation of carbon-centered radical at Glu, Cys, and Gly.

Olivier Mozziconacci et al.

Chemical research in toxicology, 25(9), 1842-1861 (2012-06-21)

Glutathione thiyl radicals (GS(•)) were generated in H(2)O and D(2)O by either exposure of GSH to AAPH, photoirradiation of GSH in the presence of acetone, or photoirradiation of GSSG. Detailed interpretation of the fragmentation pathways of deuterated GSH and GSH

Automated microextraction by packed sorbent of cannabinoids from human urine using a lab-made device packed with molecularly imprinted polymer.

Douglas Morisue Sartore et al.

Talanta, 219, 121185-121185 (2020-09-06)

An original, selective and automated method, for the microextraction by packed sorbent (MEPS) of Δ9-tetrahydrocannabinol (THC), 11-hydroxy-Δ9-tetrahydrocannabinol (THC-OH), and 11-nor-Δ9-tetrahydrocannabinol-9-carboxylic acid (THC-COOH) from human urine, was developed by using (i) a catechin-molded molecularly imprinted polymer (MIP), (ii) a new lab-made

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2,2-偶氮二(2-甲基丙基咪) 二盐酸盐

powder or granules, 97%