2,2-偶氮二(2-甲基丙基咪) 二盐酸盐

Name: 2,2-偶氮二(2-甲基丙基咪) 二盐酸盐
Brand: ALDRICH

powder or granules, 97%

别名:

2,2′-偶氮二异丁基脒二盐酸盐, AAPH

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关于此项目

线性分子式:

[=NC(CH₃)₂C(=NH)NH₂]₂·2HCl

化学文摘社编号:

2997-92-4

分子量:

271.19

Beilstein:

3718854

EC 号:

221-070-0

MDL编号:

MFCD00142725

UNSPSC代码:

12162002

PubChem化学物质编号:

24867630

NACRES:

NA.23

主要文件

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质量水平

200

方案

97%

表单

powder or granules

t_1/2

10 hr(56 °C)

mp

175-177 °C (lit.)

溶解性

acetone, dioxane, methanol, ethanol, DMSO and water: soluble

SMILES字符串

Cl.Cl.CC(C)(\N=N\C(C)(C)C(N)=N)C(N)=N

InChI

1S/C8H18N6.2ClH/c1-7(2,5(9)10)13-14-8(3,4)6(11)12;;/h1-4H3,(H3,9,10)(H3,11,12);2*1H/b14-13+;;

InChI key

LXEKPEMOWBOYRF-QDBORUFSSA-N

应用

自由基引发剂。
丙烯酸、乙烯基、烯丙基单体聚合反应的引发剂。

特点和优势

可发生一级分解形成阳离子型自由基。在紫外光照射下分解。与阳离子表面活性剂相容。分解速率取决于 pH 值。

象形图

GHS02,GHS07,GHS09

警示用语：

Danger

危险声明

H251,H302,H317,H319,H410

预防措施声明

P235 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338

危险分类

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Self-heat. 1 - Skin Sens. 1

储存分类代码

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Exogenous glutathione is essential in the testing of antioxidant capacity using radical-induced haemolysis.

Nitya Jani et al.

Journal of pharmacological and toxicological methods, 65(3), 142-146 (2012-04-18)

Radical-induced haemolysis has been employed by many investigators to determine the antioxidant capacity of novel compounds. However the free radical generator 2,2'-azobis (2-amidinopropane) dihydrochloride (AAPH) results in the complete depletion of intracellular reduced glutathione (GSH) in cells that can no

Nature of interactions between PEO-PPO-PEO triblock copolymers and lipid membranes: (I) effect of polymer hydrophobicity on its ability to protect liposomes from peroxidation.

Jia-Yu Wang et al.

Biomacromolecules, 13(9), 2616-2623 (2012-07-20)

PEO-PPO-PEO triblock copolymers have opposing effects on lipid membrane integrity: they can behave either as membrane sealants or as membrane permeabilizers. To gain insights into their biomembrane activities, the fundamental interactions between a series of PEO-based polymers and phospholipid vesicles

Synthesis of 4-methylcoumarin derivatives containing 4,5-dihydropyrazole moiety to scavenge radicals and to protect DNA.

Chuan Xiao et al.

European journal of medicinal chemistry, 53, 159-167 (2012-04-24)

A series of 4-methylcoumarin derivatives containing 4,5-dihydropyrazole moiety were synthesized and their antioxidant activities were evaluated in AAPH (2,2'-azobis(2-amidinopropane hydrochloride))-induced oxidation of DNA, and in trapping DPPH (2,2'-diphenyl-1-picrylhydrazyl) and ABTS(+•) (2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate) cationic radical), respectively. Among coumarin derivatives, 3a-d and 4a-c

A new oxidative stress model, 2,2-azobis(2-amidinopropane) dihydrochloride induces cardiovascular damages in chicken embryo.

Rong-Rong He et al.

PloS one, 8(3), e57732-e57732 (2013-03-08)

It is now well established that the developing embryo is very sensitive to oxidative stress, which is a contributing factor to pregnancy-related disorders. However, little is known about the effects of reactive oxygen species (ROS) on the embryonic cardiovascular system

Intramolecular hydrogen transfer reactions of thiyl radicals from glutathione: formation of carbon-centered radical at Glu, Cys, and Gly.

Olivier Mozziconacci et al.

Chemical research in toxicology, 25(9), 1842-1861 (2012-06-21)

Glutathione thiyl radicals (GS(•)) were generated in H(2)O and D(2)O by either exposure of GSH to AAPH, photoirradiation of GSH in the presence of acetone, or photoirradiation of GSSG. Detailed interpretation of the fragmentation pathways of deuterated GSH and GSH

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2,2-偶氮二(2-甲基丙基咪) 二盐酸盐

powder or granules, 97%