441171
(溴甲基)环丁烷
97%
别名:
环丁基甲基溴
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关于此项目
线性分子式:
C4H7CH2Br
化学文摘社编号:
分子量:
149.03
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
(溴甲基)环丁烷, 97%
InChI
1S/C5H9Br/c6-4-5-2-1-3-5/h5H,1-4H2
SMILES string
BrCC1CCC1
InChI key
FLHFTXCMKFVKRP-UHFFFAOYSA-N
assay
97%
form
liquid
refractive index
n20/D 1.48 (lit.)
bp
123-124 °C (lit.)
density
1.326 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
Application
用于 10-酮吗啡喃类似物的合成，以及他们与三种阿片受体结合的研究。
General description
(Bromomethyl)cyclobutane (bromomethyl-cyclobutane) is an aryl fluorinated building block. Its reaction with various hydroxychromen-4-one derivatives in the presence of anhydrous K2CO3/dry acetone and Bu4N+I- (PTC) has been investigated.
signalword
Warning
hcodes
Hazard Classifications
Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
105.8 °F - closed cup
flash_point_c
41 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Markus Nett et al.
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The natural proteasome inhibitor salinosporamide A from the marine bacterium Salinispora tropica is a promising drug candidate for the treatment of multiple myeloma and mantle cell lymphoma. Using a comprehensive approach that combined chemical synthesis with metabolic engineering, we generated
Michael Decker et al.
Journal of medicinal chemistry, 53(1), 402-418 (2009-11-26)
The phenolic group of the potent mu and kappa opioid morphinan agonist/antagonists cyclorphan and butorphan was replaced by phenylamino and benzylamino groups including compounds with para-substituents in the benzene ring. These compounds are highly potent mu and kappa ligands, e.g.
Photochemical synthesis and antimicrobial studies of new chromen-4-one based vinyl ethers.
Yusuf M, et al.
Arabian Journal of Chemistry (2013)
Cyclopropylmethyl-and cyclobutylmethyllithium by an arene-catalyzed lithiation. Stability and reactivity.
Pe?afiel I, et al.
Tetrahedron, 66(16), 2928-2935 (2010)
Ao Zhang et al.
Journal of medicinal chemistry, 47(1), 165-174 (2003-12-30)
A series of 10-ketomorphinan analogues were synthesized, and their binding affinity at all three opioid receptors was investigated. In most cases, high affinity at micro and kappa receptors, and lower affinity at delta receptor was observed, resulting in good selectivity
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