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经验公式(希尔记法):
C10H16
化学文摘社编号:
分子量:
136.23
UNSPSC Code:
12352205
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-856-6
Beilstein/REAXYS Number:
1902767
MDL number:
Assay:
99%
Form:
liquid
产品名称
(1 S )-(+)-3-卡林, 99%
InChI key
BQOFWKZOCNGFEC-BDAKNGLRSA-N
InChI
1S/C10H16/c1-7-4-5-8-9(6-7)10(8,2)3/h4,8-9H,5-6H2,1-3H3/t8-,9+/m1/s1
SMILES string
[H][C@@]12CC=C(C)C[C@]1([H])C2(C)C
assay
99%
form
liquid
optical activity
[α]20/D +17°, neat
refractive index
n20/D 1.472 (lit.)
bp
170-172 °C (lit.)
density
0.865 g/mL at 25 °C (lit.)
Quality Level
Application
(1S)-(+)-3-蒈烯已作为标准品被用于通过快速气相色谱-质谱(FGC-EI/MS)定量测定薰衣草精油中的成分。它可作为(+)-烯醇全合成的起始材料。它还可用于合成(1S,3S,4S,6R)-3,7,7-三甲基-4-吗啉代-4-基-双环(4.1.0)庚烷-3-醇,它可以高对映选择性催化向不同的醛上添加二乙基锌。
用于制备二环[3.2.0]庚烯的手性结构单元,二环[3.2.0]庚烯是合成 (+)-三甲基二氧三环壬烷和三并五元环倍半萜两个对映体的中间体。可转化为对应的联烯基烯丙基醚,用于研究其热异构化作用。二(4-异蒈烷基)硼烷的前体,是烯烃不对称硼氢化反应的试剂。
General description
(1S)-(+)-3-蒈烯是一种单萜烯。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
116.6 °F - closed cup
flash_point_c
47 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Dulcere, J.-P. et al.
The Journal of Organic Chemistry, 58, 5702-5702 (1993)
Xiaofeng Zhu et al.
Environmental entomology, 49(3), 586-592 (2020-03-22)
Scolytus schevyrewi Semenov (Coleoptera: Curculionidae: Scolytinae) is native to China and Central Asia. Damage by the adults and larvae weakens local apricot trees (Armeniaca spp.), often causing death to many host trees. In previous studies, freshly cut apricot logs were
Traumatic resin defense in Norway spruce (Picea abies): methyl jasmonate-induced terpene synthase gene expression, and cDNA cloning and functional characterization of (+)-3-carene synthase.
Faldt J, et al.
Plant Molecular Biology, 51(1), 119-133 (2003)
Enantioselective addition of diethylzinc to aldehydes catalyzed by a ?-amino alcohol derived from (+)-3-carene.
Joshi SN and Malhotra SV.
Tetrahedron Asymmetry, 14(13), 1763-1766 (2003)
Lavandula stoechas essential oil from Spain: Aromatic profile determined by gas chromatography-mass spectrometry, antioxidant and lipoxygenase inhibitory bioactivities.
Carrasco A, et al.
Industrial Crops and Products, 73, 16-27 (2015)
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