443328
N -异丙基- N -甲基- 叔 -丁胺
98%
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关于此项目
线性分子式:
(CH3)3CN(CH3)CH(CH3)2
化学文摘社编号:
分子量:
129.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
N -异丙基- N -甲基- 叔 -丁胺, 98%
InChI
1S/C8H19N/c1-7(2)9(6)8(3,4)5/h7H,1-6H3
SMILES string
CC(C)N(C)C(C)(C)C
InChI key
WYLLBTPEHIVUKV-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.419 (lit.)
bp
127 °C (lit.)
density
0.767 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
Application
N-异丙基-N-甲基叔丁胺可用于稳定硼烷-THF 溶液。通过 Sonogashira 偶联，它也可以用于合成轮烷。
General description
N-异丙基-N-甲基叔丁胺是叔胺。由 N--异丙基 N--甲基叔丁胺稳定的 BH3.THF 可用于羰基还原。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
48.2 °F - closed cup
flash_point_c
9 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
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Potyen M, et al.
Organic Process Research & Development, 11(2), 210-214 (2007)
Xiaogen Huang et al.
Organic letters, 9(9), 1793-1795 (2007-04-03)
[reaction: see text] The enantioselective borane reduction of O-benzyloxime ethers to primary amines was studied under catalytic conditions using the spiroborate esters 5-10 derived from nonracemic 1,2-amino alcohols and ethylene glycol. Effective catalytic conditions were achieved using only 10% of
Dominic Thibeault et al.
Molecules (Basel, Switzerland), 15(5), 3709-3730 (2010-07-27)
The number of synthetic methods enabling the preparation of ammonium-based rotaxanes has increased very rapidly in the past ten years. The challenge in the synthesis of rotaxanes results from the rather weak interactions between the ammonium-containing rod and the crown
Jeffrey A Crank et al.
Journal of the American Society for Mass Spectrometry, 20(10), 1790-1800 (2009-08-12)
Second generation ionic liquid matrices are developed, examined, and tested. They have shown a wide mass detection range (<1000 Da to >270,000 Da) for proteins and peptides with greater S/N ratios than solid matrices. These ionic liquid matrices also exhibit
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