InChI
1S/C12H10O.C12H10/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-3-7-11(8-4-1)12-9-5-2-6-10-12/h1-10H;1-10H
SMILES string
c1ccc(cc1)-c2ccccc2.O(c3ccccc3)c4ccccc4
InChI key
MHCVCKDNQYMGEX-UHFFFAOYSA-N
refractive index
n20/D 1.590
Quality Level
functional group
phenoxy, phenyl
General description
Dowtherm® A 是一种热稳定的有机传热流体，由高度稳定的化合物、联苯和二苯基氧化物的共晶混合物组成。Dowtherm® A 适用于高达 400°C 的高温传热应用。这种流体可用于液相和气相系统。
Application
Dowtherm® A 可作为高沸点溶剂用于环化反应。例如，它可用于合成：
- 从 2-氯-3-甲酰基喹啉合成 1-羟基-5-甲氧基-1,2-二氢苯并[f][2,7]萘啶。
- 通过取代哒嗪类的分子内 Diels-Alder 环加成反应合成异吲哚酮衍生物。
- 热条件下通过 2-二氧基磷酸-3-甲氧基丙烯酸酯分子内环化合成磷酸化氮杂环。
Legal Information
DOWTHERM is a registered trademark of The Dow Chemical Company or an affiliated company of Dow
signalword
Warning
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
V M Sheĭbak et al.
Gigiena i sanitariia, (4)(4), 81-82 (2008-12-23)
Experiments on rats were carried out to study the effect of dinil on the animals on chronic intake of the agent in the quantities exceeding the maximum permissible concentrations by many times. Despite few biochemical changes, there was a certain
[2 cases of acute dinil poisoning].
A N Kapustina et al.
Gigiena truda i professional'nye zabolevaniia, (3)(3), 50-51 (1983-03-01)
F O Dorgelo et al.
International archives of occupational and environmental health, 56(2), 129-134 (1985-01-01)
A study was carried out in a nylon producing plant to determine exposure to Dowtherm A from frequently occurring leaks in the heating system. The daily exposure to both diphenyl and diphenylether of 20 workers was determined over seven consecutive
Efficient synthesis of phosphorylated ortho-fused azaheterocycles
Modranka J and Janecki T
Tetrahedron, 67(49), 9595-9601 (2011)
An experimental study of small-diameter wickless heat pipes operating in the temperature range 200 C to 450 C.
Jouhara H and Robinson AJ.
Heat Transfer Engineering, 30(13), 1041-1048 (2009)
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