446955
烯丙基三甲氧基硅烷
95%
别名:
Trimethoxy-2-propen-1-ylsilane, trimethoxy-2-propenylsilane
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关于此项目
线性分子式:
H2C=CHCH2Si(OCH3)3
化学文摘社编号:
分子量:
162.26
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-855-8
Beilstein/REAXYS Number:
2350745
MDL number:
assay
95%
form
liquid
refractive index
n
bp
146-148 °C (lit.)
density
0.963 g/mL at 25 °C (lit.)
functional group
silyl
SMILES string
CO[Si](CC=C)(OC)OC
InChI
1S/C6H14O3Si/c1-5-6-10(7-2,8-3)9-4/h5H,1,6H2,2-4H3
InChI key
LFRDHGNFBLIJIY-UHFFFAOYSA-N
Application
Allyltrimethoxysilane is an allylating reagent that can be used for the allylation of carbonyl compounds such as aldehydes, ketones, and imines. Homoallylic alcohols and amines are obtained via the C-C bond forming reaction. It can also be used to synthesize homoallylic α-branched amines from aromatic and aliphatic aldehyde hydrazones, and ketone hydrazones.
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警示词
Warning
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
存储类别
3 - Flammable liquids
怎么回事？
WGK 3
闪点 (F)
114.8 °F - closed cup
闪点 (°C)
46 °C - closed cup
PPE（个人防护设备）
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter