447056
(S)-(-)-2-乙酰氧基丙酰氯
97%
别名:
2-过氧乙酰丙酰氯, AP-Cl
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关于此项目
线性分子式:
CH3CH(O2CCH3)COCl
化学文摘社编号:
分子量:
150.56
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
420-610-4
Beilstein/REAXYS Number:
1722943
MDL number:
Assay:
97%
Form:
liquid
Quality Segment
assay
97%
form
liquid
optical activity
[α]20/D −31°, c = 4 in chloroform
refractive index
n20/D 1.423 (lit.)
bp
50 °C/5 mmHg (lit.)
density
1.189 g/mL at 25 °C (lit.)
functional group
acyl chloride, ester
SMILES string
C[C@H](OC(C)=O)C(Cl)=O
InChI
1S/C5H7ClO3/c1-3(5(6)8)9-4(2)7/h3H,1-2H3/t3-/m0/s1
InChI key
ALHZEIINTQJLOT-VKHMYHEASA-N
Application
常用手性结构单元。也用于分解二环α-羟基内酯以及制备手性膦酸酯，以用于无保护氨基酸的对映体过量检测。有效的手性衍生剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B - Skin Sens. 1
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter