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Merck
CN

447145

硼烷二甲基硫醚络合物 溶液

5.0 M in diethyl ether

别名:

BMS, 三氢 [硫代双 [甲烷]] 硼

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关于此项目

线性分子式:
(CH3)2S · BH3
化学文摘社编号:
分子量:
75.97
UNSPSC Code:
12352112
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3663489
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InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

SMILES string

B.CSC

InChI key

RMHDLBZYPISZOI-UHFFFAOYSA-N

reaction suitability

reagent type: reductant

concentration

5.0 M in diethyl ether

bp

~34 °C

density

0.789 g/mL at 25 °C

functional group

thioether

storage temp.

2-8°C

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Application

用作区域选择性还原剂的反应物

涉及的反应物:
  • 硼氢化/氧化
笼状化合物的合成
Borane dimethyl sulfide complex can be used in the preparation of:
  • An amine-based polymer for CO2 uptake.
  • Amine-modified electrospun ultrafine fibers used to remove methyl orange from water.
  • Thexylborane, a key intermediate for the synthesis of polyethylene derived star copolymers and terpolymers.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 1 - Repr. 1B - STOT SE 3 - Water-react 1

target_organs

Central nervous system

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 1

flash_point_f

-31.0 °F - closed cup

flash_point_c

-35 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis of well-defined polyethylene-based 3-miktoarm star copolymers and terpolymers
Zhang Z, et al.
Macromolecules, 49(7), 2630-2638 (2016)
Amine modified electrospun PIM-1 ultrafine fibers for an efficient removal of methyl orange from an aqueous system
Satilmis B and Uyar T
Applied Surface Science, 453, 220-229 (2018)
Enhancement of CO2 affinity in a polymer of intrinsic microporosity by amine modification
Mason CR, et al.
Macromolecules, 47(3), 1021-1029 (2014)
Andrew J Saykin et al.
Alzheimer's & dementia : the journal of the Alzheimer's Association, 11(7), 792-814 (2015-07-22)
Genetic data from the Alzheimer's Disease Neuroimaging Initiative (ADNI) have been crucial in advancing the understanding of Alzheimer's disease (AD) pathophysiology. Here, we provide an update on sample collection, scientific progress and opportunities, conceptual issues, and future plans. Lymphoblastoid cell
A Burchert et al.
Leukemia, 29(6), 1331-1335 (2015-02-26)
A minority of chronic myeloid leukemia (CML) patients is capable of successfully discontinuing imatinib. Treatment modalities to increase this proportion are currently unknown. Here, we assessed the role of interferon alpha 2a (IFN) on therapy discontinuation in a previously reported

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