447536
2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷
95%
别名:
Tetramethylethylene chlorophosphite
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关于此项目
经验公式（希尔记法）:
C6H12ClO2P
化学文摘社编号:
分子量:
182.59
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
95%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率
n20/D 1.471 (lit.)
沸点
81.5-82 °C/13 mmHg (lit.)
密度
1.149 g/mL at 25 °C (lit.)
SMILES字符串
CC1(C)OP(Cl)OC1(C)C
InChI
1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3
InChI key
WGPCXYWWBFBNSS-UHFFFAOYSA-N
应用
2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷(TMDP)可用于：
- 作为试剂用于将醇类和杂原子亲核体类化合物通过亚磷酰化(phosphitylation)反应合成有用的糖基供体和配体。
- 作为亚磷酰化试剂将木质素样品衍生化用于31P NMR分析。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Angelov, C. M.; Dahl, O.
Tetrahedron Letters, 24, 1643-1643 (1983)
One-pot synthesis of 2-deoxy-β-oligosaccharides
Pongdee R, et al.
Organic Letters, 3(22), 3523-3525 (2001)
Lucía Penín et al.
Molecules (Basel, Switzerland), 25(2) (2020-01-24)
Eucalyptus nitens wood samples were subjected to consecutive stages of hydrothermal processing for hemicellulose solubilization and delignification with an ionic liquid, i.e., either 1-butyl-3-methylimidazolium hydrogen sulfate or triethylammonium hydrogen sulfate. Delignification experiments were carried out a 170 C for 10-50
Ethanol organosolv lignin-based rigid polyurethane foam reinforced with cellulose nanowhiskers
Li Y and Ragauskas AJ
Royal Society of Chemistry Advances, 2(8), 3347-3351 (2012)
Nontemplate-dependent polymerization processes: polyhydroxyalkanoate synthases as a paradigm
Stubbe J, et al.
Annual Review of Biochemistry, 74(22), 433-480 (2005)
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