2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷

Name: 2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷
Brand: ALDRICH

95%

别名:

Tetramethylethylene chlorophosphite

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经验公式（希尔记法）:

C₆H₁₂ClO₂P

化学文摘社编号:

14812-59-0

分子量:

182.59

NACRES:

NA.22

PubChem Substance ID:

24868346

UNSPSC Code:

12352005

MDL number:

MFCD00274239

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InChI

1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3

SMILES string

CC1(C)OP(Cl)OC1(C)C

InChI key

WGPCXYWWBFBNSS-UHFFFAOYSA-N

assay

95%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.471 (lit.)

bp

81.5-82 °C/13 mmHg (lit.)

density

1.149 g/mL at 25 °C (lit.)

Quality Level

200

Application

2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷(TMDP)可用于：

作为试剂用于将醇类和杂原子亲核体类化合物通过亚磷酰化(phosphitylation)反应合成有用的糖基供体和配体。
作为亚磷酰化试剂将木质素样品衍生化用于³¹P NMR分析。

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

0000532601

0000528015

0000528014

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Kraft lignin-based rigid polyurethane foam

Li Y and Ragauskas AJ

J. Wood Chem. Technol., 32(3), 210-224 (2012)

Guo, Y.; Sulikowski, G. A.,

Journal of the American Chemical Society, 120, 1392-1392 (1998)

One-pot synthesis of 2-deoxy-β-oligosaccharides

Pongdee R, et al.

Organic Letters, 3(22), 3523-3525 (2001)

Angelov, C. M.; Dahl, O.

Tetrahedron Letters, 24, 1643-1643 (1983)

Catalytic Transesterification of Starch with Plant Oils: A Sustainable and Efficient Route to Fatty Acid Starch Esters.

Zafer Söyler et al.

ChemSusChem, 10(1), 182-188 (2016-11-23)

The transesterification of maize starch with olive oil or high oleic sunflower oil was studied under homogeneous conditions in the presence of 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as catalyst. Most importantly, this method used two renewable resources directly, without any pretreatment or derivatization

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2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷

95%

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关于此项目

主要文件

属性

InChI

SMILES string

InChI key

assay

reaction suitability

refractive index

bp

density

Quality Level

说明

Application

安全信息

pictograms

signalword

hcodes

pcodes

Hazard Classifications

supp_hazards

存储类别

wgk

flash_point_f

flash_point_c

ppe

文件

分析证书(COA)

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