447536
2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷
95%
别名:
Tetramethylethylene chlorophosphite
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关于此项目
经验公式（希尔记法）:
C6H12ClO2P
化学文摘社编号:
分子量:
182.59
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Quality Level
assay
95%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n20/D 1.471 (lit.)
bp
81.5-82 °C/13 mmHg (lit.)
density
1.149 g/mL at 25 °C (lit.)
SMILES string
CC1(C)OP(Cl)OC1(C)C
InChI
1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3
InChI key
WGPCXYWWBFBNSS-UHFFFAOYSA-N
Application
2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷(TMDP)可用于：
- 作为试剂用于将醇类和杂原子亲核体类化合物通过亚磷酰化(phosphitylation)反应合成有用的糖基供体和配体。
- 作为亚磷酰化试剂将木质素样品衍生化用于31P NMR分析。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
相关内容
Phosphine Ligand Application Guide
Guo, Y.; Sulikowski, G. A.,
Journal of the American Chemical Society, 120, 1392-1392 (1998)
Kraft lignin-based rigid polyurethane foam
Li Y and Ragauskas AJ
J. Wood Chem. Technol., 32(3), 210-224 (2012)
One-pot synthesis of 2-deoxy-β-oligosaccharides
Pongdee R, et al.
Organic Letters, 3(22), 3523-3525 (2001)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 447536-5G | 04061832288628 |
| 447536-1G | 04061838119834 |