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Merck
CN

450995

氯化锰

AnhydroBeads™, −10 mesh, 99.999% trace metals basis

别名:

二氯化锰, 黄钙橄石

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关于此项目

线性分子式:
MnCl2
化学文摘社编号:
7773-01-5
分子量:
125.84
NACRES:
NA.23
PubChem Substance ID:
24868596
UNSPSC Code:
12352302
MDL number:
MFCD00011114
Assay:
99.999% trace metals basis
Grade:
synthesis grade

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InChI

1S/2ClH.Mn/h2*1H;/q;;+2/p-2

SMILES string

Cl[Mn]Cl

InChI key

GLFNIEUTAYBVOC-UHFFFAOYSA-L

grade

synthesis grade

product line

AnhydroBeads™

assay

99.999% trace metals basis

reaction suitability

core: manganese

impurities

≤15.0 ppm Trace Metal Analysis

particle size

−10 mesh

mp

652 °C (lit.)

density

2.98 g/mL at 25 °C (lit.)

application(s)

battery precursors
catalysts
electroplating
material synthesis precursor

Quality Level

100

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相关类别

Application

通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构，在基态时具有 24 个不成对电子。还用于形成可用于自由基环化反应的活性 Mn(0) 物质。

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2

target_organs

Brain

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000522304
0000522304
0000056141
0000063568
0000036203

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Abbati, G.L. et al.
Inorganic Chemistry, 37, 1430-1430 (1998)
Tang, J. et al.
Tetrahedron, 55, 1893-1893 (1999)
Jerome A Roth et al.
Neurotoxicology, 35, 121-128 (2013-01-15)
Chronic exposure to Mn results in the development of a neurological disorder known as manganism characterized by neurological deficits resembling that seen in Parkinsonism. Although dopaminergic neurons within the nigrostriatal pathway appear intact, Mn-induced irregularities in DA transmission have been
Geoffrey J Topping et al.
Medical physics, 40(4), 042502-042502 (2013-04-06)
Manganese(II) is employed as a contrast agent with magnetic resonance imaging (MRI) for study of neuronal activation in rats and mice. However, at the concentrations required for MRI, Mn may induce pharmacological or toxic effects. Positron emission tomography (PET) imaging
Anne Bertrand et al.
NeuroImage, 64, 693-702 (2012-09-11)
The impairment of axonal transport by overexpression or hyperphosphorylation of tau is well documented for in vitro conditions; however, only a few studies on this phenomenon have been conducted in vivo, using invasive procedures, and with contradictory results. Here we
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