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Merck
CN

450995

Sigma-Aldrich

氯化锰

AnhydroBeads™, −10 mesh, 99.999% trace metals basis

别名:

二氯化锰, 黄钙橄石

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关于此项目

线性分子式:
MnCl2
CAS Number:
7773-01-5
分子量:
125.84
MDL编号:
MFCD00011114
UNSPSC代码:
12352302
PubChem化学物质编号:
24868596
NACRES:
NA.23

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等级

synthesis grade

质量水平

100

产品线

AnhydroBeads™

方案

99.999% trace metals basis

反应适用性

core: manganese

杂质

≤15.0 ppm Trace Metal Analysis

粒径

−10 mesh

mp

652 °C (lit.)

密度

2.98 g/mL at 25 °C (lit.)

应用

battery precursors
catalysts
electroplating
material synthesis precursor

SMILES字符串

Cl[Mn]Cl

InChI

1S/2ClH.Mn/h2*1H;/q;;+2/p-2

InChI key

GLFNIEUTAYBVOC-UHFFFAOYSA-L

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相关类别

应用

通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构，在基态时具有 24 个不成对电子。还用于形成可用于自由基环化反应的活性 Mn(0) 物质。

法律信息

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

警示用语：

Danger

危险声明

H301,H318,H373

危险分类

Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2

靶器官

Brain

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000056141
0000063568
0000036203
FJ3478
MKBS8883V

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Abbati, G.L. et al.
Inorganic Chemistry, 37, 1430-1430 (1998)
Tang, J. et al.
Tetrahedron, 55, 1893-1893 (1999)
Elizabeth Greally et al.
Journal of cardiovascular magnetic resonance : official journal of the Society for Cardiovascular Magnetic Resonance, 15, 4-4 (2013-01-18)
Manganese-enhanced cardiovascular magnetic resonance (MECMR) can non-invasively assess myocardial calcium influx, and calcium levels are known to be elevated in muscular dystrophy cardiomyopathy based on cellular studies. Left ventricular functional studies and MECMR were performed in mdx mice (model of
Tora Sund Morken et al.
Pediatric research, 73(2), 171-179 (2012-11-24)
Hypoxia-ischemia (HI) induces delayed inflammation and long-term gray and white matter brain injury that may be altered by hyperoxia. HI and 2 h of hyperoxia (100% O2) or room air (21% O2) in 7-d-old (P7) rats were studied by magnetic resonance
M R Sepúlveda et al.
Contrast media & molecular imaging, 7(4), 426-434 (2012-06-01)
Manganese is a vital element and cofactor of many key enzymes, but it is toxic at high levels, causing pronounced disturbances in the mammalian brain. Magnetic resonance imaging (MRI) studies using manganese ions as a paramagnetic contrast agent are often
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