454427
甲基二苯基氧化膦
98%
别名:
Diphenylmethylphosphine oxide, Methyldiphenyloxophosphine, NSC 407134
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关于此项目
线性分子式:
CH3P(C6H5)2(O)
化学文摘社编号:
分子量:
216.22
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
218-346-8
MDL number:
assay
98%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp
111-115 °C (lit.)
functional group
phosphine
SMILES string
CP(=O)(c1ccccc1)c2ccccc2
InChI
1S/C13H13OP/c1-15(14,12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
InChI key
PEGCITODQASXKH-UHFFFAOYSA-N
Application
Catalyst for:
- Chlorination and bromination (halogenation) of alcohols under Appel conditions
- Hydrosilylation reactions
- Enantioselective cyanosilylation of ketones
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
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全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 454427-5G | 04061833314289 |
| 454427-25G | 04061833417157 |