454427
甲基二苯基氧化膦
98%
别名:
Diphenylmethylphosphine oxide, Methyldiphenyloxophosphine, NSC 407134
方案
98%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
111-115 °C (lit.)
官能团
phosphine
SMILES字符串
CP(=O)(c1ccccc1)c2ccccc2
InChI
1S/C13H13OP/c1-15(14,12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
InChI key
PEGCITODQASXKH-UHFFFAOYSA-N
应用
- Chlorination and bromination (halogenation) of alcohols under Appel conditions
- Hydrosilylation reactions
- Enantioselective cyanosilylation of ketones
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
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