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Merck
CN

456772

4-羧基苯硼酸

别名:

4-(二羟基硼烷基)苯甲酸, 4-硼酸苯甲酸, 4-羟基羰基苯基硼酸, 4-羧基苯基硼酸, 4-羧基苯硼酸, NSC 221170, 对硼酸苯甲酸, 对羧基苯基硼酸, 对羧基苯硼酸

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关于此项目

线性分子式:
HO2CC6H4B(OH)2
化学文摘社编号:
分子量:
165.94
PubChem Substance ID:
UNSPSC Code:
12352103
NACRES:
NA.22
EC Index Number:
604-189-6
Beilstein/REAXYS Number:
3031088
MDL number:
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InChI

1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10)

SMILES string

OB(O)c1ccc(cc1)C(O)=O

InChI key

SIAVMDKGVRXFAX-UHFFFAOYSA-N

mp

220 °C (dec.) (lit.)

functional group

carboxylic acid

Quality Level

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Application

作为反应物参与:
  • 与聚苯乙烯胶乳表面稳定链的缩合反应
  • Suzuki偶联反应
  • 酯化
  • 聚乙烯胺衍生化
  • 同位素标记汞的合成
  • 聚SiNW官能化用于检测多巴胺
作为试剂用于
  • Suzuki-Miyaura交叉偶联反应
  • NIR荧光染料诱导的pH敏感度对量子点荧光寿命的影响
  • 生物负载的钯纳米颗粒,作为水中Suzuki反应的无磷催化剂
  • 在室温下与芳基硼酸一起进行Chan-Lam型铜(Cu)催化的S-芳基化

作为试剂用于
  • 通过区域选择性Suzuki-Miyaura交叉偶联反应结合钯催化的分子内氨基羰基化和环化反应制备异喹啉酮
  • 制备安普那韦基P1取代双芳基衍生物,是超有效的HIV-1蛋白酶抑制剂
  • 以空气为氧化剂,通过可见光引发、钌(Ru)-配合物催化的芳基硼酸有氧氧化羟基化反应制备苯酚
  • 葡萄糖敏感性含硼嵌段共聚物
  • 制备三磺化杯芳烃上层磺酰胺基衍生物及其与三甲基赖氨酸表观遗传标记的配合物

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

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Hai Wang et al.
Journal of colloid and interface science, 590, 103-113 (2021-02-02)
The self-healing mechanism and bioelectrochemical interface properties of supramolecular gels have been rarely explored. In this context, we propose a constitutive "fibril-reorganization" model to reveal the self-healing mechanism of a series of core-shell structured guanosine-borate (GB) hydrogels and emphasize that
Xiu Ye et al.
Nanomaterials (Basel, Switzerland), 9(5) (2019-05-10)
Aggregation-induced emission (AIE) active cellulose nanocrystals (TPE-CNCs) were synthesized by attaching tetraphenylethylene (TPE) to cellulose nanocrystals (CNCs). The structure and morphology of TPE-CNCs were characterized by FT-IR, XRD, ζ-potential measurements, elemental analysis, TEM, atomic force microscopy (AFM), and dynamic laser
Jinqiang Wang et al.
Science advances, 5(7), eaaw4357-eaaw4357 (2019-07-17)
Glucose-responsive insulin delivery systems with robust responsiveness that has been validated in animal models, especially in large animal models, remain elusive. Here, we exploit a new strategy to form a micro-sized complex between a charge-switchable polymer with a glucose-sensing moiety
Muthusamy Selvaraj et al.
Analytica chimica acta, 1066, 112-120 (2019-04-28)
A new boronic acid derivative functionalized with a 4-(3-(4-(4,5-diphenyl-1H-imidazole-2-yl)phenyl)-1,2,4-oxadiazol-5-yl)phenyl (IOP) moiety was synthesized for use as a sequential "on-off-on"-type relay fluorescence probe for Fe3+ ions and F- ions with high selectivity and sensitivity under physiological conditions. The introduction of Fe3+
Kentaro Yoshida et al.
Polymers, 12(8) (2020-08-23)
Phenylboronic acid-bearing polyamidoamine dendrimer (PBA-PAMAM)/poly(vinyl alcohol) (PVA) multilayer films were prepared through the layer-by-layer (LbL) deposition of PBA-PAMAM solution and PVA solution. PBA-PAMAM/PVA films were constructed successfully through the formation of boronate ester bonds between the boronic acid moiety in

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