Quality Level
assay
97%
form
solid
reaction suitability
core: ammonium
mp
170 °C (dec.) (lit.)
functional group
amine
SMILES string
[F-].C[N+](C)(C)C
InChI
1S/C4H12N.FH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI key
GTDKXDWWMOMSFL-UHFFFAOYSA-M
Application
四甲基氟化铵可以与硫酰氟组合使用，以用于将芳基酚转化为芳基氟化物。它可以与氨基硅烷反应，从而原位产生鎓酰胺碱，该产物可使杂芳烃去质子化。
作为如下过程的反应物：
- 卤化物诱导的2-取代氮丙啶鎓盐开环
- 通过氟代脱氢反应合成氟代芳烃
- 通过卤代交换氟化法在离子液体中合成七氟醚
- 氟化聚（氧钼酸盐）的合成
可用于卤素交换。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Nucleophilic deoxyfluorination of phenols via aryl Fluorosulfonate intermediates.
Schimler SD, et al.
Journal of the American Chemical Society, 139(4), 1452-1455 (2017)
Use of tetramethylammonium fluoride (TMAF) and alkali metal alkoxides as an activator for catalytic deprotonative functionalization of heteroaromatic C (sp2)?H bonds.
Inamoto K, et al.
Tetrahedron, 70(43), 7917-7922 (2014)
Martin-Louis Y Riu et al.
Science advances, 6(13), eaaz3168-eaaz3168 (2020-04-02)
This exploratory synthesis investigation was undertaken to determine the viability of replacing a single carbon vertex with another p-block element in a highly strained tetrahedrane molecule. Phosphorus was selected for this purpose because the stable molecular form of elemental phosphorus
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 459135-1G | 04061832343044 |
| 459135-5G | 04061832343051 |