Quality Level
reaction suitability
reagent type: reductant
concentration
0.4 M in hexanes
bp
68-70 °C
density
0.691 g/mL at 25 °C
SMILES string
B1C2CCCC1CCC2
InChI
1S/C8H15B/c1-3-7-5-2-6-8(4-1)9-7/h7-9H,1-6H2/t7-,8+
InChI key
FEJUGLKDZJDVFY-OCAPTIKFSA-N
Application
烯烃保护基团†
反应物用于：
反应物用于：
- 线性SPPS合成泛素衍生物
- 铜催化有机硼化合物与伯烷基卤化物和拟卤化物发生交叉偶联反应
- 将烯烃分子内插入钯-氮键
- 制备(膦酰基乙酰基)鸟氨酸以研究对酵母中精氨酸生物合成基因的影响
- Hetero-Diels-Alder反应合成螺环生物碱
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signalword
Danger
target_organs
Central nervous system, Nervous system
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3 - Water-react. 1
法规信息
危险化学品
此项目有
Jefferson D Revell et al.
Organic letters, 7(5), 831-833 (2005-02-25)
1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity
A Ganesan
Mini reviews in medicinal chemistry, 6(1), 3-10 (2006-02-07)
Solid-phase synthesis is a powerful tool for achieving high-throughput chemistry. This review discusses recent diverse examples from my group: the solid-phase synthesis of unsymmetrical guanidines, polymer-supported versions of cyclooctadiene and 9-BBN, a triflate-like linker, the synthesis of tetrahydro-beta-carbolines by the
Yi Luan et al.
Organic letters, 13(9), 2510-2513 (2011-04-09)
Diazo esters, arylboranes, and carbamoyl imines undergo a 3-component Mannich condensation reaction. Catalyzed by Cu(II) salts, the reaction affords the corresponding isocyanate Mannich product: one that can be easily trapped in situ by other nucleophiles. The Mannich condensation corresponds to
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 459496-100ML | 04061832343174 |
| 459496-1L | 04061838127976 |