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Merck
CN

46093

1-乙基-3-甲基咪唑六氟磷酸盐

≥97.0% (HPLC)

别名:

EMIMPF6

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关于此项目

经验公式(希尔记法):
C6H11F6N2P
化学文摘社编号:
分子量:
256.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥97.0% (HPLC)
Form:
solid
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产品名称

1-乙基-3-甲基咪唑六氟磷酸盐, ≥97.0% (HPLC)

InChI key

DPDAKOVGQUGTHH-UHFFFAOYSA-N

SMILES string

F[P-](F)(F)(F)(F)F.CCn1cc[n+](C)c1

InChI

1S/C6H11N2.F6P/c1-3-8-5-4-7(2)6-8;1-7(2,3,4,5)6/h4-6H,3H2,1-2H3;/q+1;-1

assay

≥97.0% (HPLC)

form

solid

mp

58-62 °C (lit.)
58-62 °C

Quality Level

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Other Notes

空气和水中均稳定的铵盐,在适度高温下为离子液体,可用于熔盐技术

General description

1-Ethyl-3-methylimidazolium hexafluorophosphate is a task-specific ionic liquid (TSIL) with low melting point.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Rotational dynamics of a diatomic solute in the room-temperature ionic liquid 1-ethyl-3-methylimidazolium hexafluorophosphate
Shim, Youngseon, et al.
J. Chem. Phys. , 125.6 (2006)
Molecular dynamics studies of melting and some liquid-state properties of 1-ethyl-3-methylimidazolium hexafluorophosphate [emim][PF 6]
Alavi, Saman, and Donald L. Thompson
J. Chem. Phys. , 122.15, 154704-154704 (2005)
High-pressure phase behavior of systems with ionic liquids: II. The binary system carbon dioxide+ 1-ethyl-3-methylimidazolium hexafluorophosphate
Shariati, Alireza, and Cor J. Peters
Journal of Supercritical Fluids, 25.2, 109-117 (2003)
High-pressure phase behavior of systems with ionic liquids: II. The binary system carbon dioxide+ 1-ethyl-3-methylimidazolium hexafluorophosphate
Shariati, A., and C. J. Peters
Journal of Supercritical Fluids, 29.1, 43-48 (2004)
J. Fuller et al.
Journal of the Chemical Society. Chemical Communications, 299-299 (1994)

商品

Functionalized imidazolium cations with thioether, urea, or thiourea derivatized side chains act as metal-ligating moieties, whereas the PF6– anions provide the desired water immiscibility.

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