460990
反-次亚硝酸钠 水合物
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线性分子式:
Na2N2O2 · xH2O
化学文摘社编号:
分子量:
105.99 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
solid
InChI
1S/H2N2O2.2Na.H2O/c3-1-2-4;;;/h(H,1,4)(H,2,3);;;1H2/q;2*+1;/p-2
SMILES string
[Na+].[Na+].[H]O[H].[O-]\N=N\[O-]
InChI key
MNTPJDLNJKAOKU-UHFFFAOYSA-L
form
solid
storage temp.
2-8°C
Quality Level
Application
叔丁基连二次硝酸盐的前体，该盐用于叔丁氧基自由基的低温热生成。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Gregory A Poskrebyshev et al.
Journal of the American Chemical Society, 126(3), 891-899 (2004-01-22)
All major properties of the aqueous hyponitrite radicals (ONNO- and ONNOH), the adducts of nitric oxide (NO) and nitroxyl (3NO- and 1HNO), are revised. In this work, the radicals are produced by oxidation of various hyponitrite species in the 2-14
Nan Xu et al.
Inorganic chemistry, 49(14), 6253-6266 (2010-07-30)
Nitric oxide (NO) and its derivatives such as nitrite and hyponitrite are biologically important species of relevance to human health. Much of their physiological relevance stems from their interactions with the iron centers in heme proteins. The chemical reactivities displayed
The structure of the hyponitrite species in a heme Fe-Cu binuclear center.
Constantinos Varotsis et al.
Angewandte Chemie (International ed. in English), 46(13), 2210-2214 (2007-02-14)
Jun Wang et al.
Journal of the American Chemical Society, 131(2), 450-451 (2008-12-23)
A iron-dinitrosyl species ((6)L)Fe(NO)(2) (2), generated from nitrogen monoxide (*NO) binding to its related iron(II)-mononitrosyl complex ((6)L)Fe(NO) (1), efficiently effects reductive coupling of two *NO molecules to release nitrous oxide (N(2)O), when Cu(+) ion and 2 equiv acid are added;
Nan Xu et al.
Journal of the American Chemical Society, 131(7), 2460-2461 (2009-02-05)
The coupling of two nitric oxide (NO) molecules in heme active sites is an important contributor to the conversion of NO to nitrous oxide (N(2)O) by heme-containing enzymes. Several formulations for the presumed heme-Fe{N(2)O(2)}(n-) intermediates have been proposed previously, however
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