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Merck
CN

46188

法尼醛,异构体混合物

technical

别名:

3,7,11-三甲基-2,6,10-十二烷三烯醛

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关于此项目

经验公式(希尔记法):
C15H24O
化学文摘社编号:
分子量:
220.35
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
242-957-9
Beilstein/REAXYS Number:
1723427
MDL number:
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InChI key

YHRUHBBTQZKMEX-YFVJMOTDSA-N

InChI

1S/C15H24O/c1-13(2)7-5-8-14(3)9-6-10-15(4)11-12-16/h7,9,11-12H,5-6,8,10H2,1-4H3/b14-9+,15-11+

SMILES string

[H]C(=O)\C=C(/C)CC\C=C(/C)CC\C=C(/C)C

grade

technical

impurities

≤3% water

refractive index

n20/D >1.4920 (lit.), n20/D 1.497

bp

126-129 °C/3.5 mmHg (lit.)

density

0.909 g/mL at 25 °C (lit.)

functional group

aldehyde

Quality Level

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General description

据报告,法呢醛是醛酮还原酶1B10(AKR1B10)的特异性脂质底物。法呢醇与布朗葡萄藻B种族菌株的原生质体一起培养导致法呢醛和3-羟基-2,3-二氢法呢醛的形成。

Application

法呢醛用于倍半萜烯纳纳莫尔的合成。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 2

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Anna Luxová et al.
Chirality, 16(4), 228-233 (2004-03-23)
The absolute configurations of citronellol, 2,3-dihydrofarnesol, and 2,3-dihydrofarnesal in male marking pheromones of seven species of bumblebees and cuckoo bumblebees were determined by enantioselective gas chromatography on a capillary column coated with 60% heptakis(2,3-di-O-acetyl-6-O-TBDMS)-beta-cyclodextrin in polysiloxane PS 268. Pure (-)-S-enantiomers
H Inoue et al.
Biochemical and biophysical research communications, 196(3), 1401-1405 (1993-11-15)
Farnesal and 3-hydroxy-2,3-dihydrofarnesal (3-hydroxy-3,7,11-trimethyl-6,10-dodecadiene-1-al) were formed from farnesol when the alcohol was incubated with the protoplast of Botryococcus braunii B race strain. This fact suggests the existence of farnesal hydratase in the alga. Feeding experiments showed that both farnesal and
Kenji Shimomura et al.
Journal of chemical ecology, 36(8), 824-833 (2010-07-08)
Callosobruchus rhodesianus (Pic) (Coleoptera: Chrysomelidae: Bruchinae) is a pest of stored legumes through the Afro-tropical region. In laboratory bioassays, males of C. rhodesianus were attracted to volatiles collected from virgin females. Collections were purified by various chromatographic techniques, and the
Grace Jones et al.
The FEBS journal, 273(21), 4983-4996 (2006-10-27)
The in vivo ligand-binding function and ligand-binding activity of the Drosophila melanogaster retinoid-X receptor (RXR) ortholog, ultraspiracle, toward natural farnesoid products of the ring gland were assessed. Using an equilibrium fluorescence-binding assay, farnesoid products in the juvenile hormone (JH) biosynthesis
W R Tschantz et al.
The Journal of biological chemistry, 276(4), 2321-2324 (2000-11-18)
Prenylated proteins contain either a 15-carbon farnesyl or a 20-carbon geranylgeranyl isoprenoid covalently attached via a thioether bond to a cysteine residue at or near their C terminus. As prenylated proteins comprise up to 2% of the total protein in

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