46210
(+)-葑酮
purum, ≥98.0% (sum of enantiomers, GC)
别名:
(+)-1,3,3-三甲基-2-降冰片酮, (1S)-1,3,3-三甲基二环[2.2.1]庚-2-酮
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关于此项目
经验公式（希尔记法）:
C10H16O
化学文摘社编号:
分子量:
152.23
UNSPSC Code:
12352212
NACRES:
NA.22
PubChem Substance ID:
EC Number:
225-160-0
Beilstein/REAXYS Number:
2206555
MDL number:
产品名称
(+)-葑酮, purum, ≥98.0% (sum of enantiomers, GC)
InChI key
LHXDLQBQYFFVNW-XCBNKYQSSA-N
InChI
1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m1/s1
SMILES string
CC1(C)[C@@H]2CC[C@@](C)(C2)C1=O
grade
purum
assay
≥98.0% (sum of enantiomers, GC)
optical activity
[α]20/D +60±3°, neat
refractive index
n20/D 1.463
bp
63-65 °C/13 mmHg (lit.)
mp
5-7 °C (lit.)
density
0.945 g/mL at 20 °C (lit.)
functional group
ketone
Quality Level
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存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
150.8 °F - closed cup
flash_point_c
66 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Boris Steuer et al.
Phytochemical analysis : PCA, 14(5), 285-289 (2003-10-01)
The aim of this study was to investigate the accuracy and transferability of near-infrared (NIR) calibrations for estimating the content and composition of the volatile fraction in fennel fruits (Foeniculum vulgare Miller) as an example of medicinal and spice plants.
Philip C Bulman Page et al.
The Journal of organic chemistry, 67(22), 7787-7796 (2002-10-26)
The first two stable enantiomerically pure chiral N-H oxaziridines, derived from camphor and fenchone, are shown to act as electrophilic sources of nitrogen upon reaction with various carbon nucleophiles. Nitrogen is transferred, together with the camphor/fenchone unit, when deprotonated esters
Dirk W Lachenmeier et al.
Journal of agricultural and food chemistry, 56(9), 3073-3081 (2008-04-19)
Thirteen samples of authentic absinthe dating from the preban era (i.e., prior to 1915) were analyzed for parameters that were hypothesized as contributing to the toxicity of the spirit, including naturally occurring herbal essences (thujone, pinocamphone, fenchone), methanol, higher alcohols
Hua-Zhen Qin et al.
Zhong yao cai = Zhongyaocai = Journal of Chinese medicinal materials, 34(12), 1897-1899 (2012-04-17)
To study the components of volatile oil of Alpinia henryi. The volatile oil was extracted by steam distillation method,used gaseous phase-mass spectrum combination method (GC-MS) to analyze the components of volatile oil. 58 kinds of components were isolated, among them
Yoshio Kasashima et al.
Journal of oleo science, 58(8), 421-427 (2009-07-09)
Intramolecular etherification of 1,3-diols was investigated using iodine as a catalyst under solvent-free conditions. The reaction proceeded to completion in a heterogeneous system. Five-membered cyclic ethers were obtained by intramolecular cyclization of 1,3-diols with dehydration. A propella ether (11-oxatricyclo[4.4.3.0(1,6)]tridecane) was
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