464015
(S)-(+)-2-苄基-1-(对甲苯磺酰基)氮丙啶
98%
别名:
(S)-2-Benzyl-1-tosylaziridine
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关于此项目
经验公式（希尔记法）:
C16H17NO2S
化学文摘社编号:
分子量:
287.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
Assay:
98%
assay
98%
optical activity
[α]20/D +8.8°, c = 1.3 in toluene
mp
92-94 °C (lit.)
functional group
phenyl, sulfonamide
SMILES string
Cc1ccc(cc1)S(=O)(=O)N2C[C@@H]2Cc3ccccc3
InChI
1S/C16H17NO2S/c1-13-7-9-16(10-8-13)20(18,19)17-12-15(17)11-14-5-3-2-4-6-14/h2-10,15H,11-12H2,1H3/t15-,17?/m0/s1
InChI key
ISURUORMAKCTFF-MYJWUSKBSA-N
Application
(S)-(+)-2-Benzyl-1-(p-tolylsulfonyl)aziridine can be used:
- To prepare tert-butyl(S)-6-((4-methylphenyl)sulfonamido)-3-oxo-7-phenylheptanoate, an intermediate for the synthesis of substituted octahydroindoles.
- In the preparation of ortho-bromo phenethylamine products, which are further used to synthesize chiral 2-substituted indolines.
- In the synthesis of β-aryltelluro amines as potent carbonic anhydrase inhibitors.
(S)-(+)-2-Benzyl-1-(p-tolylsulfonyl)aziridine may be used in the preparation of (R)-ethyl (5-benzyl-2-oxo-1-tosyl)pyrrolidine-3-carboxylate by reacting with diethyl potassiomalonate.
