464643
1-Cbz-4-哌啶酮
99%
别名:
1-苄氧羰基-4-哌啶酮, N-CBZ-4-哌啶酮, N-苄氧羰基-4-哌啶酮
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关于此项目
经验公式（希尔记法）:
C13H15NO3
化学文摘社编号:
分子量:
233.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1533716
Assay:
99%
assay
99%
refractive index
n20/D 1.542 (lit.)
bp
114-140 °C/0.25 mmHg (lit.)
density
1.172 g/mL at 25 °C (lit.)
functional group
ketone, phenyl
SMILES string
O=C1CCN(CC1)C(=O)OCc2ccccc2
InChI
1S/C13H15NO3/c15-12-6-8-14(9-7-12)13(16)17-10-11-4-2-1-3-5-11/h1-5H,6-10H2
InChI key
VZOVOHRDLOYBJX-UHFFFAOYSA-N
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.
Tetrahedron Letters, 42, 6943-6943 (2001)
Yong Huang et al.
Journal of the American Chemical Society, 124(33), 9662-9663 (2002-08-15)
We report the first examples of hydrogen-bond-promoted acceleration of hetero-Diels-Alder reactions and the use of such catalysis for the hetero-Diels-Alder reactions of simple, unactivated ketones. Several spiro-fused dihydropyans were synthesized in good yields using this procedure. This activation protocol represents
Biheteroaromatic diphosphine oxides-catalyzed stereoselective direct aldol reactions.
Rossi S, et al.
Tetrahedron, 67(1), 158-166 (2011)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 464643-25ML | 04061838128010 |
| 464643-100ML | 04061838128003 |
| 464643-5ML | 04061838128027 |