465585
1,3-二氯-1,1,3,3,-四甲基二硅氧烷
97%
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关于此项目
线性分子式:
(CH3)2Si(Cl)OSi(Cl)(CH3)2
化学文摘社编号:
分子量:
203.21
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-278-1
Beilstein/REAXYS Number:
1741218
MDL number:
Assay:
97%
InChI key
DMEXFOUCEOWRGD-UHFFFAOYSA-N
InChI
1S/C4H12Cl2OSi2/c1-8(2,5)7-9(3,4)6/h1-4H3
SMILES string
C[Si](C)(Cl)O[Si](C)(C)Cl
assay
97%
bp
138 °C (lit.)
density
1.039 g/mL at 25 °C (lit.)
Application
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane can be used to prepare:
- A Silicon-based fluorene polymer by reacting with a dibromofluorene derived Grignard reagent.
- ansa-Metallocene compound i.e, ansa-[TiCl2{η5:η5-(C5H4SiMe2)2O}].
- Silaanthracenophanes.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
59.0 °F - closed cup
flash_point_c
15 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis and Structures of New Silaanthracenophanes
Lee I, et al.
Bulletin of the Korean Chemical Society,, 33(1), 255-260 (2012)
Carbon-Silicon coupling between fluorenyl Grignard reagents and dichlorosilanes for synthesis of novel copolymers and chemical properties of the copolymers
Kitamura N and Yamamoto T
Applied Organometallic Chemistry, 17(11), 840-842 (2003)
Synthesis and crystal structures of μ-1, 3-bis (η5-tetramethylcyclopentadienyl)-1, 1, 3, 3-tetramethyldisiloxane)[ η2-bis (trimethylsilyl) ethyne] titanium (II) and a doubly tucked-in product of its thermolysis
Horacek M, et al.
Journal of Organometallic Chemistry, 658(1-2), 235-241 (2002)
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