产品名称
聚丁二烯，主要为 1,2-加成, approx. 90% 1,2-vinyl
InChI
1S/C4H8/c1-3-4-2/h3-4H,1-2H3/b4-3+
SMILES string
C=CC=C
InChI key
IAQRGUVFOMOMEM-ONEGZZNKSA-N
refractive index
n20/D 1.5002 (lit.)
viscosity
30-100 poise(45 °C)(lit.)
transition temp
Tg −30 °C
density
0.86 g/mL at 25 °C (lit.)
Quality Level
Application
- 四氮化学转化聚丁二烯制备氧化荧光抗氧化泡沫：本研究使用四嗪点击化学修饰聚丁二烯，以增强其性能，创建出可响应荧光氧化的抗氧化泡沫，展示利用1,2-加成聚丁二烯的创新方法（RE Bagge et al., 2017）。
- 基于异恶唑啉的多孔聚合物高效吸附2,4,6-三硝基甲苯（TNT）：原位生成的氧化腈与聚丁二烯之间的无催化剂点击聚合。本文探讨了聚丁二烯在环境净化应用中的吸附性能增强，强调了其结构特征如何影响性能（H Deng et al., 2020）。
- 用三氟甲基和可点击叠氮化物基团一次性改性聚丁二烯：本文描述了在聚丁二烯中同时引入三氟甲基和叠氮化物官能团的方法，展示了1,2加成聚丁二烯在化学修饰中的多功能性（S Wang et al., 2021）。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Jiayin Yuan et al.
Macromolecular rapid communications, 32(15), 1157-1162 (2011-06-29)
Commercially available 1,2-PB was transformed into a well-defined reactive intermediate by quantitative bromination. The brominated polymer was used as a polyfunctional macroinitiator for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline to yield a water-soluble brush polymer. Nucleophilic substitution of bromide by
Alexandra Sperschneider et al.
ACS nano, 4(10), 5609-5616 (2010-09-17)
We report on the quasi in situ scanning force microscopy nanotomography which proved to be a key method to effectively obtain a three-dimensional (3D) microdomain structure of a complex ABC triblock morphology. As an example, we studied polybutadiene-block-poly(2-vinyl pyridine)-block-poly(tert-butyl methacrylate)
Mechanochemistry: Demonstrated leverage.
Roman Boulatov
Nature chemistry, 5(2), 84-86 (2013-01-25)
Deniz Turgut et al.
PloS one, 5(12), e15551-e15551 (2010-12-24)
In recent years, there is aroused interest in expressing complex systems as networks of interacting nodes. Using descriptors from graph theory, it has been possible to classify many diverse systems derived from social and physical sciences alike. In particular, folded
Ho-Joong Kim et al.
Journal of nanoscience and nanotechnology, 13(1), 577-581 (2013-05-08)
Thermal and mechanical properties of PU/POSS nanocomposites plasticized with DOA were investigated. These hybrid materials were prepared using one-step method through the incorporation of flexible HTPB prepolymer, reactive or non-reactive POSS nanoparticle, and DOA plasticizer under IPDI curative system. The
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