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467359

(S)-(-)-4-氨基-2-羟基丁酸

Name: (<I>S</I>)-(-)-4-氨基-2-羟基丁酸
Brand: ALDRICH

96%

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关于此项目

线性分子式:

H₂NCH₂CH₂CH(OH)CO₂H

化学文摘社编号:

40371-51-5

分子量:

119.12

PubChem Substance ID:

24870402

UNSPSC Code:

12352116

NACRES:

NA.22

EC Index Number:

670-305-7

Beilstein/REAXYS Number:

1721686

MDL number:

MFCD00674110

Assay:

96%

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属性

Quality Level

100

assay

96%

optical activity

[α]23/D −30°, c = 1 in H₂O

mp

200-203 °C (lit.)

functional group

amine, carboxylic acid, hydroxyl

SMILES string

NCC[C@H](O)C(O)=O

InChI

1S/C4H9NO3/c5-2-1-3(6)4(7)8/h3,6H,1-2,5H2,(H,7,8)/t3-/m0/s1

InChI key

IVUOMFWNDGNLBJ-VKHMYHEASA-N

说明

General description

(S)-(-)-4-Amino-2-hydroxybutyric acid is an important moiety of butirosin, an aminoglycoside antibiotic.

Application

Building block for enantiopure 3-hydroxypyrrolidin-2-ones.

(S)-(-)-4-Amino-2-hydroxybutyric acid may be used in the preparation of 6′-amino-1-N-[(S)-4-amino-2-hydroxybutyryl]-6′-deoxylividomycin A.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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Synthesis of 6'-Amino-1-N-[(S)-4-Amino-2-Hydroxybutyryl]-6'-Deoxylividomycin A.

Watanabe I, et al.

Bulletin of the Chemical Society of Japan, 48(8), 2303-2305 (1975)

1-N-acylation of gentamicin C1a by a cyclic, chiral gamma-amino-alpha-hydroxy acid related to the (S)-4-amino-2-hydroxybutyric acid.

M Philippe et al.

The Journal of antibiotics, 35(11), 1507-1512 (1982-11-01)

A semisynthetic aminoglycoside antibiotic 15, containing a cyclic gamma-amino-alpha-hydroxy acid, related to the 1-N-4-amino-2-hydroxybutyric acid (AHBA) side chain of butirosins and amikacin, has been prepared. Conveniently protected 3,2',6'-tris-N-tert-butoxycarbonylgentamicin C1a (12) was condensed with the phtalimido active ester 10 to give

Synthesis of (S)-Isoserine.

Miyazawa T, et al.

Agricultural and Biological Chemistry, 40(8), 1651-1652 (1976)

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货号	GTIN
UC455-10MG	04061837410291
UC455-5MG	04061837410307
467359-5G	04061833038048
467359-25G	04061833038031