cis-1,4-二乙酰氧基-2-丁烯

Name: <I>cis</I>-1,4-二乙酰氧基-2-丁烯
Brand: ALDRICH

95%

别名:

顺-1,4-二醋酸基-2-丁烯

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所有图片(1)

About This Item

线性分子式:

CH₃CO₂CH₂CH=CHCH₂O₂CCH₃

CAS Number:

25260-60-0

分子量:

172.18

MDL编号:

MFCD00059339

UNSPSC代码:

12352100

PubChem化学物质编号:

24870459

NACRES:

NA.22

质量水平

100

方案

95%

折射率

n20/D 1.443 (lit.)

沸点

120-121 °C/18 mmHg (lit.)

密度

1.08 g/mL at 25 °C (lit.)

官能团

ester

SMILES字符串

[H]\C(COC(C)=O)=C(/[H])COC(C)=O

InChI

1S/C8H12O4/c1-7(9)11-5-3-4-6-12-8(2)10/h3-4H,5-6H2,1-2H3/b4-3-

InChI key

VZUAUHWZIKOMFC-ARJAWSKDSA-N

一般描述

cis-1,4-Diacetoxy-2-butene is an ester. Ruthenium olefin metathesis catalysts having cyclic (alkyl)(amino)carbenes effectively catalyzes the cross-metathesis of cis-1,4-diacetoxy-2-butene with allylbenzene. cis-1,4-Diacetoxy-2-butene on pyrolysis affords 1-acetoxy-1,3-butadiene, a diacetate and an isomeric 1,2-diacetoxy-3-butene. Mechanism of pyrolysis has been investigated.

应用

cis-1,4-Diacetoxy-2-butene may be used in the preparation of hindered Diels-Alder adducts. It may be used for the synthesis of 1,2,3,4-tetrahydro-2-vinylquinoxalines, via Palladium-catalyzed tandem allylation of 1,2-phenylenediamines.