468568
己基锂 溶液
2.3 M in hexane
别名:
1-Hexyllithium, n-Hexyllithium, Hexane - lithium complex
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
CH3(CH2)5Li
化学文摘社编号:
分子量:
92.11
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3600261
Concentration:
2.3 M in hexane
Form:
liquid
InChI
1S/C6H13.Li/c1-3-5-6-4-2;/h1,3-6H2,2H3;
SMILES string
[Li]CCCCCC
InChI key
RMKNFFPDYCVCDI-UHFFFAOYSA-N
form
liquid
concentration
2.3 M in hexane
bp
69 °C
density
0.708 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
General description
正己基锂是一种有机锂化合物，在有机合成中可用作强碱、烷基化剂和锂化试剂。
Application
正己基锂可用作以下反应中的烷基化剂:
- 与芳基卤进行的镍催化交叉偶联反应。
- 铜催化对映选择性烯丙基烷基化反应。
Packaging
建议将25 mL Sure/Seal™ 瓶作为一次性瓶使用。反复穿刺可能会导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 3 - Water-react 1
target_organs
Central nervous system, Nervous system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
15.8 °F - closed cup
flash_point_c
-9 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Jacqueline E Cloud et al.
Angewandte Chemie (International ed. in English), 53(52), 14527-14532 (2014-11-05)
The synthesis of colloidal nanocrystals (NCs) of lithiated group 14 elements (Z=Si, Ge, and Sn) is reported, which are Li4.4 Si, Li3.75 Si, Li4.4 Ge, and Li4.4 Sn. Lix Z compounds are highly reactive and cannot be synthesized by existing methods.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持