469602
4-苄氧基丁酸
95%
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关于此项目
线性分子式:
C6H5CH2O(CH2)3CO2H
化学文摘社编号:
分子量:
194.23
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
95%
折射率
n20/D 1.512 (lit.)
沸点
135 °C/0.3 mmHg (lit.)
密度
1.097 g/mL at 25 °C (lit.)
官能团
carboxylic acid
ether
phenyl
SMILES字符串
OC(=O)CCCOCc1ccccc1
InChI
1S/C11H14O3/c12-11(13)7-4-8-14-9-10-5-2-1-3-6-10/h1-3,5-6H,4,7-9H2,(H,12,13)
InChI key
CXEFZVVLTJQWBF-UHFFFAOYSA-N
一般描述
4-Benzyloxybutyric acid can be synthesized from γ-butyrolactone. It participates in the asymmetric total synthesis of erythromycin.
应用
4-Benzyloxybutyric acid may be used in the synthesis of benzyloxybutyryl (BOB) esters of alcohols by standard acylation techniques or by the Jacobsen asymmetric nucleophilic ring opening of epoxides.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
Synthesis of tylonolide, the aglycone of tylosin.
Masamune S, et al.
Journal of the American Chemical Society, 104(20), 5523-5526 (1982)
Asymmetric total synthesis of erythromcin. 1. Synthesis of an erythronolide A secoacid derivative via asymmetric induction.
Woodward RB, et al.
Journal of the American Chemical Society, 103(11), 3210-3213 (1981)
What about BOB? A synthetically useful protecting group.
Clark MA and Ganem B.
Tetrahedron Letters, 41(49), 9523-9526 (2000)
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