469785
苄基缩水甘油醚
99%
别名:
(±)-O-苄基缩水甘油, (苄氧基甲基)环氧乙烷, (苯基甲氧基)甲基]环氧乙烷, 1-(苄氧基)-2,3-环氧丙烷, 2-[(苯基甲氧基)甲基]环氧乙烷, 2-[[(苄氧基)甲基]氧基]环氧乙烷, 3-(苄氧基)-1,2-环氧丙烷, 缩水甘油基苄醚
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关于此项目
经验公式（希尔记法）:
C10H12O2
化学文摘社编号:
分子量:
164.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
220-899-5
MDL number:
Assay:
99%
InChI key
QNYBOILAKBSWFG-UHFFFAOYSA-N
InChI
1S/C10H12O2/c1-2-4-9(5-3-1)6-11-7-10-8-12-10/h1-5,10H,6-8H2
SMILES string
C(OCc1ccccc1)C2CO2
assay
99%
refractive index
n20/D 1.5170 (lit.)
bp
70-73 °C/11 mmHg (lit.)
density
1.077 g/mL at 25 °C (lit.)
functional group
ether, phenyl
storage temp.
2-8°C
Quality Level
General description
苄基缩水甘油醚是一种缩水甘油衍生物。 Rac -( R )-苄基缩水甘油醚参与无规和等规线性聚 1,2-甘油碳酸酯的合成。黄色蠕形霉对外消旋苄基缩水甘油醚的生物催化拆分进行了描述。30%ee 的苄基缩水甘油醚至 ( S )-苄基缩水甘油醚和 40%ee 的 ( R )-3-苄氧基丙烷-1,2-二醇的全 嗜碱芽孢杆菌 拆分反应已有报道。它与 K -，K + （15-冠-5） 2 反应生成甘氨酰氧钾和联苄。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Youlin Pan et al.
Chemistry, an Asian journal, 12(11), 1198-1203 (2017-03-21)
Cyclic azasilanes have been synthesized for the purpose of developing coupling agents appropriate for a variety of nanotechnologies including surface modification of nanoparticles, nanocrystals, mesoporous materials and substrates. N-Methyl-aza-2,2,4-trimethylsilacyclopentane is representative of this class of compounds. Preliminary data for the
Selective cleavage of the linear ether bond in benzyl glycidyl ether and triphenylmethyl glycidyl ether by potassium alkalide as two-electron-transfer reagent.
Grobelny Z, et al.
Journal of Organometallic Chemistry, 660(1), 6-13 (2002)
Chun Wei et al.
Biotechnology letters, 34(8), 1499-1503 (2012-04-25)
Talaromyces flavus containing a constitutive epoxide hydrolase (EH) resolved racemic benzyl glycidyl ether and nine derivatives into their (R)-enantiomers. After optimization of the fermentation conditions, the specific EH activity and biomass concentration were improved from 13.5 U/g DCW and 14.8
Feng Xue et al.
International journal of biological macromolecules, 146, 80-88 (2020-01-01)
A gene encoding a halohydrin dehalogenase from Pseudomonas pohangensis (PpHHDH) was identified, synthesized and expressed in Escherichia coli. Subsequently, we used protein engineering to enhance the enzyme's enantioselectivity. We created two enantiocomplementary HHDH mutants, N160L and Q159L, which exhibited higher
Qingjie Zhang et al.
Nanomaterials (Basel, Switzerland), 8(9) (2018-09-12)
A surface-sizing technique was offered to take full advantage of multi-walled carbon nanotubes (MWCNTs) and epoxy resins. Two surface-sizing treated MWCNTs were obtained through a ball-milling treatment of amino-functionalized MWCNTs (MWCNT-NH₂) with n-butyl glycidylether (BuGE) and benzyl glycidylether (BeGE). These
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