469785
苄基缩水甘油醚
99%
别名:
(±)-O-苄基缩水甘油, (苄氧基甲基)环氧乙烷, (苯基甲氧基)甲基]环氧乙烷, 1-(苄氧基)-2,3-环氧丙烷, 2-[(苯基甲氧基)甲基]环氧乙烷, 2-[[(苄氧基)甲基]氧基]环氧乙烷, 3-(苄氧基)-1,2-环氧丙烷, 缩水甘油基苄醚
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关于此项目
经验公式（希尔记法）:
C10H12O2
化学文摘社编号:
分子量:
164.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
220-899-5
MDL number:
产品名称
苄基缩水甘油醚, 99%
InChI key
QNYBOILAKBSWFG-UHFFFAOYSA-N
InChI
1S/C10H12O2/c1-2-4-9(5-3-1)6-11-7-10-8-12-10/h1-5,10H,6-8H2
SMILES string
C(OCc1ccccc1)C2CO2
assay
99%
refractive index
n20/D 1.5170 (lit.)
bp
70-73 °C/11 mmHg (lit.)
density
1.077 g/mL at 25 °C (lit.)
functional group
ether
phenyl
storage temp.
2-8°C
Quality Level
General description
苄基缩水甘油醚是一种缩水甘油衍生物。 Rac -( R )-苄基缩水甘油醚参与无规和等规线性聚 1,2-甘油碳酸酯的合成。黄色蠕形霉对外消旋苄基缩水甘油醚的生物催化拆分进行了描述。30%ee 的苄基缩水甘油醚至 ( S )-苄基缩水甘油醚和 40%ee 的 ( R )-3-苄氧基丙烷-1,2-二醇的全 嗜碱芽孢杆菌 拆分反应已有报道。它与 K -，K + （15-冠-5） 2 反应生成甘氨酰氧钾和联苄。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Chun Wei et al.
Biotechnology letters, 34(8), 1499-1503 (2012-04-25)
Talaromyces flavus containing a constitutive epoxide hydrolase (EH) resolved racemic benzyl glycidyl ether and nine derivatives into their (R)-enantiomers. After optimization of the fermentation conditions, the specific EH activity and biomass concentration were improved from 13.5 U/g DCW and 14.8
Selective cleavage of the linear ether bond in benzyl glycidyl ether and triphenylmethyl glycidyl ether by potassium alkalide as two-electron-transfer reagent.
Grobelny Z, et al.
Journal of Organometallic Chemistry, 660(1), 6-13 (2002)
Youlin Pan et al.
Chemistry, an Asian journal, 12(11), 1198-1203 (2017-03-21)
Cyclic azasilanes have been synthesized for the purpose of developing coupling agents appropriate for a variety of nanotechnologies including surface modification of nanoparticles, nanocrystals, mesoporous materials and substrates. N-Methyl-aza-2,2,4-trimethylsilacyclopentane is representative of this class of compounds. Preliminary data for the
Qingjie Zhang et al.
Nanomaterials (Basel, Switzerland), 8(9) (2018-09-12)
A surface-sizing technique was offered to take full advantage of multi-walled carbon nanotubes (MWCNTs) and epoxy resins. Two surface-sizing treated MWCNTs were obtained through a ball-milling treatment of amino-functionalized MWCNTs (MWCNT-NH₂) with n-butyl glycidylether (BuGE) and benzyl glycidylether (BeGE). These
Priya Saini et al.
World journal of microbiology & biotechnology, 33(5), 82-82 (2017-04-06)
In order to produce enantiomerically pure epoxides for the synthesis of value-added chemicals, a novel putative epoxide hydrolase (EH) sgeh was cloned and overexpressed in pET28a/Escherichia coli BL21(DE3). The 1047 bp sgeh gene was mined from Streptomyces griseus NBRC 13350 genome
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