471240
N-丁基二乙醇胺
≥98.6%
别名:
2,2′-丁基亚氨基二乙醇, N,N-双(2-羟乙基)丁胺
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关于此项目
线性分子式:
CH3(CH2)3N(CH2CH2OH)2
化学文摘社编号:
分子量:
161.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-055-0
Beilstein/REAXYS Number:
1739642
MDL number:
Assay:
≥98.6%
vapor density
5.5 (vs air)
Quality Level
vapor pressure
1 mmHg ( 25 °C)
assay
≥98.6%
refractive index
n20/D 1.463 (lit.)
bp
273-275 °C/741 mmHg (lit.)
mp
−70 °C (lit.)
density
0.986 g/mL at 25 °C (lit.)
functional group
amine, hydroxyl
SMILES string
CCCCN(CCO)CCO
InChI
1S/C8H19NO2/c1-2-3-4-9(5-7-10)6-8-11/h10-11H,2-8H2,1H3
InChI key
GVNHOISKXMSMPX-UHFFFAOYSA-N
General description
N -丁基二乙醇胺（ N - N -丁基二乙醇胺）是叔胺。作为 N -取代的二乙醇胺配体。它与铬 (II) 和镧系元素 (III)/稀土盐 (Ln = La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y) 在共配体存在的情况下发生反应，得到 3 个系列的同构 1:1 3d (Cr (III))/4f (Ln (III)) 配位簇化合物。
Application
N-丁基二乙醇胺（H2bdea，N-n-丁基二乙醇胺）已用于合成以下配合物（Hdnba = 3,5-二硝基苯甲酸；Hpta =p-甲苯甲酸；H2tpa =对苯二甲酸）：
- 新单核 [Cu(Hbdea)2]·2Hdnba ，双核[Cu2(β-Hbdea)2(N3)2] 和[Cu2(β-Hbdea)2(pta)2]·2H2O
- 1D 聚合物 \ [Cu 2 （μHbdea） 2 （μ-tpa）] n ·2nH 2 O 铜 (II) 化合物
- 四核 3d-4f 单分子磁体 (SMM) 复合物
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
265.1 °F - closed cup
flash_point_c
129.5 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Julia Rinck et al.
Inorganic chemistry, 54(7), 3107-3117 (2015-03-11)
Reactions of the N-substituted diethanolamine ligand N-n-butyldiethanolamine with chromium(II) and lanthanide(III)/rare earth salts (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y) in the presence of coligands give access to three series
Katrin R Gruenwald et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 2109-2120 (2009-03-11)
The new mononuclear [Cu(Hbdea)(2)].2Hdnba (), dinuclear [Cu(2)(mu-Hbdea)(2)(N(3))(2)] () and [Cu(2)(mu-Hbdea)(2)(pta)(2)].2H(2)O (), and 1D polymeric [Cu(2)(mu-Hbdea)(2)(mu-tpa)](n).2nH(2)O () copper(II) compounds have been prepared by self-assembly, in aqueous alkali medium and at ambient conditions, from Cu(II) acetate, N-butyldiethanolamine (H(2)bdea) and the corresponding auxiliary
Stuart K Langley et al.
Inorganic chemistry, 54(7), 3631-3642 (2015-03-24)
Six tetranuclear 3d–4f single-molecule magnet (SMM) complexes formed using N-n-butyldiethanolamine and N-methyldiethanolamine in conjunction with ortho- and para-substituted benzoic acid and hexafluoroacetoacetone ligands yield two families, both having a butterfly metallic core. The first consists of four complexes of type
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 471240-500ML | 04061832359670 |
| 471240-2L | 04061837019715 |