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线性分子式:
CH3SO2Cl
化学文摘社编号:
分子量:
114.55
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-706-1
Beilstein/REAXYS Number:
506297
MDL number:
Assay:
≥99.7%
InChI key
QARBMVPHQWIHKH-UHFFFAOYSA-N
InChI
1S/CH3ClO2S/c1-5(2,3)4/h1H3
SMILES string
CS(Cl)(=O)=O
assay
≥99.7%
Quality Level
bp
60 °C/21 mmHg (lit.)
density
1.48 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Application
甲磺酰氯可用于伯醇的甲磺酸化,以合成相应的甲磺酸盐。它也可以用于将胺转化为相应的磺酰胺。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Methanesulfonyl Chloride.
Vaillancourt V
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Water-solvent method for tosylation and mesylation of primary alcohols promoted by KOH and catalytic amines.
Morita J I
Green Chemistry, 7(10), 711-715 (2005)
Base-free monosulfonylation of amines using tosyl or mesyl chloride in water
Kamal A
Tetrahedron Letters, 49(2), 348-353 (2008)
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The Journal of organic chemistry, 85(5), 2945-2955 (2020-02-06)
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