471593
N,N-二乙基羟胺
≥98%
别名:
N-Hydroxydiethylamine, DEHA, Diethylhydroxylamine
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关于此项目
线性分子式:
(CH3CH2)2NOH
化学文摘社编号:
分子量:
89.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
223-055-4
Beilstein/REAXYS Number:
1731349
MDL number:
Assay:
≥98%
InChI key
FVCOIAYSJZGECG-UHFFFAOYSA-N
InChI
1S/C4H11NO/c1-3-5(6)4-2/h6H,3-4H2,1-2H3
SMILES string
CCN(O)CC
vapor density
3.07 (vs air)
vapor pressure
4 mmHg ( 0 °C)
assay
≥98%
expl. lim.
10 %
Quality Level
bp
125-130 °C (lit.)
mp
−26-−25 °C (lit.)
density
0.867 g/mL at 25 °C (lit.)
functional group
amine
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General description
N,N-二乙基羟胺（二乙基羟胺，DEHA，C2H5)2NOH）是一种N,N-二烷基羟胺。已经通过各种理论和光谱方法研究了它与清洁硅(100)-2x1表面的相互作用。据报道，在DEHA的光化学氧化过程中，可形成了H2O2以及超氧化物和二乙基氮氧化物自由基。
Application
N,N-二乙基羟胺可用作制备不对称混合配体噁二唑啉和/或亚胺铂配合物的配体。它可用于合成混合酰肼的有机金属团簇/锌的羟基酰胺簇。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
113.0 °F - closed cup
flash_point_c
45 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Hyunsung Mun et al.
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Iminoacylation of acetone oxime Me(2)C[double bond, length as m-dash]NOH upon reaction with trans-[PtCl(2)(NCCH(2)CO(2)Me)(2)] and [2 + 3] cycloaddition of acyclic nitrone (-)O(+)N(Me) = C(H)(C(6)H(4)Me-4) to a nitrile ligand in lead to the formation of mono-imine trans-[PtCl(2)(imine-a)(NCCH(2)CO(2)Me)] [imine-a = NH[double bond
J Heicklen
Annals of the New York Academy of Sciences, 502, 145-159 (1987-01-01)
Photochemical smog is caused by a free-radical chain mechanism which converts NO to NO2. The NO2 further reacts to produce ozone, nitric acid, and peracylnitrates. This chain mechanism can be inhibited by suitable free-radical scavengers. The chemistry and toxicology of
C C Reddy et al.
Journal of toxicology and environmental health, 15(3-4), 467-475 (1985-01-01)
The effects of diethylhydroxylamine (DEHA), a potent free-radical scavenger, on lipid peroxidation of rat liver microsomes were investigated in vitro. DEHA strongly inhibited ascorbate-dependent nonenzymatic microsomal lipid peroxidation. DEHA also completely inhibited nonenzymatic lipid peroxidation of heat-denatured microsomes, indicating that
Chronic inhalation study of mice subjected to diethylhydroxylamine, nitroethane, and diethylamine hydrogen sulfite.
J Heicklen et al.
Environmental research, 27(2), 277-289 (1982-04-01)
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