471933
4-碘苯硼酸
≥95.0%
别名:
B-(4-iodophenyl)-boronic acid, p-Iodophenylboronic acid, p-iodo-benzeneboronic acid
质量水平
方案
≥95.0%
mp
326-330 °C (lit.)
官能团
iodo
SMILES字符串
OB(O)c1ccc(I)cc1
InChI
1S/C6H6BIO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChI key
PELJYVULHLKXFF-UHFFFAOYSA-N
应用
试剂用于
试剂用于制备
- 铜介导的无配体好氧氟烷基化
- 钯催化的好氧氧化交叉偶联反应
- 用于 Suzuki 偶联反应的可回收磁性纳米离子负载的钯催化剂
- 使用铜（Cu）催化剂的氧化羟基化
- 无配体钯催化的 Suzuki-Miyaura 交叉偶联
- 使用金盐催化剂的同型偶联
- 钌（Ru）催化的交叉偶联
- CuI 催化的 Suzuki 偶联反应
- 钯催化的多米诺骨牌 Heck-Mizoroki/Suzuki-Miyaura 反应
- 三乙酸锰介导的芳基硼酸向烯烃的自由基加成
试剂用于制备
- 通过“点击化学”策略合成截短侧耳素衍生物，进行用于研究与核糖体结合和抗菌活性
- 液晶聚乙炔衍生物
其他说明
含不定量的酸酐
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Hong Li et al.
Chemical communications (Cambridge, England), 47(27), 7880-7882 (2011-06-11)
The first ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acids is reported. Various aliphatic and aromatic aldehydes are transformed to the corresponding arylketones. A total of 31 examples with moderate to excellent yields are presented, together with the results of an
Samir Yahiaoui et al.
The Journal of organic chemistry, 76(8), 2433-2438 (2011-03-23)
A palladium(II)-catalyzed Heck-Mizoroki/Suzuki-Miyaura domino reaction involving metal coordinating dimethylaminoethyl vinyl ethers and a number of electron-rich and electron-deficient arylboronic acids has been developed. Through variation of the temperature and the concentration of the p-benzoquinone (p-Bq) ligand/reoxidant, conditions for the robust
An efficient and recyclable magnetic-nanoparticle-supported palladium catalyst for the Suzuki coupling reactions of organoboronic acids with alkynyl bromides
X. Zhang, et al.,
Synthesis, 18, 2975-2983 (2011)
Kazuhiko Tsukagoshi et al.
Journal of chromatography. A, 1123(1), 106-112 (2006-05-24)
Molecular recognition of mono- and disaccharides was performed making use of the interaction between their diol groups and p-iodophenylboronic acid in capillary electrophoresis (CE) with a chemiluminescence (CL) detection system. p-Iodophenylboronic acid acted as an enhancer for luminol-horseradish peroxidase-hydrogen peroxide
Kiyofumi Inamoto et al.
Chemical communications (Cambridge, England), 47(42), 11775-11777 (2011-10-01)
Copper-catalysed oxidative hydroxylation of arylboronic acids was accomplished in water containing an amphiphilic surfactant, providing facile access to phenol derivatives.
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