473324
1-氯-2-甲基丁烷
96%
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关于此项目
线性分子式:
C2H5CH(CH3)CH2Cl
化学文摘社编号:
分子量:
106.59
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
210-466-9
MDL number:
Assay:
96%
产品名称
1-氯-2-甲基丁烷, 96%
InChI key
IWAKWOFEHSYKSI-UHFFFAOYSA-N
InChI
1S/C5H11Cl/c1-3-5(2)4-6/h5H,3-4H2,1-2H3
SMILES string
CCC(C)CCl
assay
96%
refractive index
n20/D 1.412 (lit.)
bp
100 °C/750 mmHg (lit.)
density
0.886 g/mL at 25 °C (lit.)
functional group
alkyl halide
chloro
Quality Level
General description
1-Chloro-2-methylbutane is a halogenated organic building block. It can be synthesized by employing 2-methylbutanol as starting reagent. Grignard reagent derived from (+)-1-chloro-2-methylbutane may be employed for the preparation of partially optically active (-)-alkylphenylcarbinols and partially optically active secondary carbinols. Infrared and Raman spectra of its optically active form (+)(S)-1-chloro-2-methylbutane in various phases (liquid, glass and crystal) have been evaluated.
Asymmetric Reductions. VI. The Action of the Grignard Reagent from (+)-1-Chloro-2-methylbutane on a Series of Alkyl t-Butyl Ketones1.
Foley WM, et al.
Journal of the American Chemical Society, 81(11), 2779-2784 (1959)
Asymmetric Reductions. VII. the Action of the Grignard Reagent from (+)-1-chloro-2-methylbutane on a Series of Alkyl Phenyl Ketones1-3.
MacLeod R, et al.
Journal of the American Chemical Society, 82(4), 876-880 (1960)
Synthetic inhibitors of Alcohol dehydrogenase. 4-Substituted alkyl and cycloalkylpyrazoles.
Tolf BR, et al.
Acta Chemica Scandinavica, 33, 483-487 (1979)
Infrared and Raman spectra and normal frequencies calculation of isomeric (+)(S)-1-chloro-2-methylbutane.
Schettino V and Benedetti E.
Spectrochimica Acta Part A: Molecular Spectroscopy, 34(3), 353-356 (1978)
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