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线性分子式:
[[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co
化学文摘社编号:
分子量:
603.74
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
InChI
1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/b37-21+,38-22+;/t29-,30-;/m1./s1
SMILES string
CC(C)(C)c1cc2C=[N@H]3[C@@H]4CCCC[C@H]4[N@@H]5=Cc6cc(cc(c6O[Co]35Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI key
ZFWPDJKMASHRPT-CITKKJEGSA-L
mp
>350 °C (lit.)
Quality Level
Application
用于末端环氧化物的水解动力学拆分和内消旋环氧化物不对称开环的催化剂。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Skin Sens. 1A - STOT RE 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Jacobsen, E.N. et al.
Tetrahedron Letters, 38, 773-773 (1997)
M Tokunaga et al.
Science (New York, N.Y.), 277(5328), 936-938 (1997-08-15)
Epoxides are versatile building blocks for organic synthesis. However, terminal epoxides are arguably the most important subclass of these compounds, and no general and practical method exists for their production in enantiomerically pure form. Terminal epoxides are available very inexpensively
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