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关于此项目
经验公式(希尔记法):
C3H6O2
化学文摘社编号:
分子量:
74.08
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
79783
Assay:
97%
assay
97%
optical activity
[α]20/D −15°, neat
optical purity
ee: 98% (GLC)
refractive index
n20/D 1.433 (lit.)
bp
66-67 °C/19 mmHg (lit.)
density
1.116 g/mL at 20 °C (lit.)
functional group
ether, hydroxyl
storage temp.
−20°C
SMILES string
OC[C@H]1CO1
InChI
1S/C3H6O2/c4-1-3-2-5-3/h3-4H,1-2H2/t3-/m0/s1
InChI key
CTKINSOISVBQLD-VKHMYHEASA-N
General description
缩水甘油或称2,3-环氧-1-丙醇是一种具有高反应活性的环氧衍生物,通常用作制备多种聚合物(如聚酯、聚碳酸酯、聚氨酯和聚酰胺)的单体。它还被用于制备洗涤剂、橡胶、香水、纺织物染料、清漆、化妆品和油漆。
Application
用于合成手性 (E)-烯丙醇侧链,该侧链可通过交叉复分解反应引入到前列环素和前列腺素骨架中。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
161.6 °F
flash_point_c
72 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
A simplified early stage assessment of process intensification: glycidol as a value-added product from epichlorohydrin industry wastes
Cespi D, et al.
Green Chemistry, 18(16), 4559-4570 (2016)
Neil A Sheddan et al.
Organic letters, 8(14), 3101-3104 (2006-06-30)
[reaction: see text] A cross metathesis (CM) approach has been successfully applied to introduce fully functionalized omega-side chain appendages of various prostacyclin and prostaglandin analogues, resulting in high (E)-selectivities for the C13-C14 double bond and leading to the total syntheses
One-pot synthesis of glycidol from glycerol and dimethyl carbonate over KF/sepiolite catalyst
Algoufi YT, et al.
Applied Catalysis A: General, 487, 181-188 (2014)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 474789-1G | 04061832361444 |
| 474789-5G | 04061832361451 |

