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Merck
CN

475262

1,3-二碘苯

98%

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关于此项目

经验公式(希尔记法):
C6H4I2
化学文摘社编号:
分子量:
329.90
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
210-921-1
MDL number:
Assay:
98%
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Quality Level

assay

98%

storage condition

protect from light

mp

34-37 °C (lit.)

functional group

iodo

storage temp.

2-8°C

SMILES string

Ic1cccc(I)c1

InChI

1S/C6H4I2/c7-5-2-1-3-6(8)4-5/h1-4H

InChI key

SFPQFQUXAJOWNF-UHFFFAOYSA-N

General description

1,3-Diiodobenzene is a halogenated benzene derivative. Its reaction with phenylboronic acid in the presence of CuI, DABCO (1,4-diazabicyclo[2.2.2]octane) and TBAB (n-Bu4NBr) has been analyzed. 1,3-Diiodobenzene undergoes coupling with 2-methylthiophene in the presence of Ir/Ag2CO3 to afford meta-linked isomer of thiophene-benzene-thiophene triad.

Application

1,3-Diiodobenzene may be used in the synthesis of:
  • 3,5-bis(perfluorodecyl)phenylboronic acid
  • epitaxially aligned and separated polyphenylene lines on Cu(110)
  • 1,3-bis(4-ethynyl-2,5-dibutoxyphenyl-1-ethynyl)benzene


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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分析证书(COA)

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3, 5-Bis (perfluorodecyl) phenylboronic acid as an easily recyclable direct amide condensation catalyst.
Ishihara K, et al.
Synlett, 2001(09), 1371-1374 (2001)
Synthesis, Chain Rigidity, and Luminescent Properties of Poly [(1, 3-phenyleneethynylene)-a lt-tris (2, 5-dialkoxy-1, 4-phenyleneethynylene)] s.
Chu Q, et al.
Macromolecules, 35(20), 7569-7574 (2002)
Jin-Heng Li et al.
The Journal of organic chemistry, 72(6), 2053-2057 (2007-02-09)
In the presence of TBAB, CuI-catalyzed Suzuki-Miyaura cross-coupling of vinyl halides and aryl halides with arylboronic acids was conducted smoothly to afford the corresponding diarylethenes and polyaryls in moderate to good yields using DABCO (1,4-diazabicyclo[2.2.2]octane) as the ligand. We also



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货号GTIN
475262-25G04061832674841
475262-5G04061832361628