47633
N-(9-芴甲氧羰基)-L-亮氨酸
≥97.0%
别名:
N-(9-芴甲氧羰基)-L-亮氨酸, Fmoc-L-亮氨酸
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关于此项目
经验公式（希尔记法）:
C21H23NO4
化学文摘社编号:
分子量:
353.41
NACRES:
NA.26
PubChem Substance ID:
eCl@ss:
32160406
UNSPSC Code:
12352209
EC Number:
252-662-7
MDL number:
Beilstein/REAXYS Number:
2178254
产品名称
N-(9-芴甲氧羰基)-L-亮氨酸, ≥97.0%
InChI key
CBPJQFCAFFNICX-IBGZPJMESA-N
InChI
1S/C21H23NO4/c1-13(2)11-19(20(23)24)22-21(25)26-12-18-16-9-5-3-7-14(16)15-8-4-6-10-17(15)18/h3-10,13,18-19H,11-12H2,1-2H3,(H,22,25)(H,23,24)/t19-/m0/s1
SMILES string
CC(C)C[C@H](NC(=O)OCC1c2ccccc2-c3ccccc13)C(O)=O
assay
≥97.0%
optical activity
[α]20/D −25±2°, c = 1% in DMF
reaction suitability
reaction type: C-H Activation
reaction type: Fmoc solid-phase peptide synthesis
reagent type: ligand
reaction type: Peptide Synthesis
mp
152-156 °C (lit.)
152-156 °C
application(s)
peptide synthesis
functional group
Fmoc
amine
carboxylic acid
storage temp.
2-8°C
Quality Level
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Application
Fmoc-Leu-OH可用作合成反应剂：
- 通过与功能化α-氨基酸盐酸盐反应合成寡肽。
- 环酯Sansalvamide A，这是在海洋真菌中发现的一种天然产物。
- Streptocidin A−D，放线菌Tü 6071中天然存在的十肽抗生素。
- 酰基二肽酰胺，可用于化妆品应用。
Biochem/physiol Actions
可诱导胰岛素敏感化，但不能诱导脂肪生成的 PPARγ 配体。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Catalytic Oligopeptide Synthesis
Liu Z, et al.
Organic Letters, 20(3), 612-615 (2018)
Rapid, high-yield, solid-phase synthesis of the antitumor antibiotic sansalvamide A using a side-chain-tethered phenylalanine building block
Lee Y and Silverman RB
Organic Letters, 2(23), 3743-3746 (2000)
Markus Beck Erlach et al.
Journal of biomolecular NMR, 69(2), 53-67 (2017-09-16)
For evaluating the pressure responses of folded as well as intrinsically unfolded proteins detectable by NMR spectroscopy the availability of data from well-defined model systems is indispensable. In this work we report the pressure dependence of
Facile solid-phase synthesis of cyclic decapeptide antibiotic streptocidins A-D
Qin C, et al.
Tetrahedron Letters, 45(1), 217-220 (2004)
Synthesis and Evaluation of Coumaroyl Dipeptide Amide as Potential Whitening Agents
Lee H-S, et al.
Bull. Korean Chem. Soc., 34(10), 3017-3021 (2013)
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