478598
邻氯苯磺酰基异氰酸酯
90%
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关于此项目
线性分子式:
ClC6H4SO2NCO
化学文摘社编号:
分子量:
217.63
UNSPSC Code:
12352100
PubChem Substance ID:
MDL number:
产品名称
邻氯苯磺酰基异氰酸酯, 90%
InChI
1S/C7H4ClNO3S/c8-6-3-1-2-4-7(6)13(11,12)9-5-10/h1-4H
SMILES string
Clc1ccccc1S(=O)(=O)N=C=O
InChI key
LALCDSDHLXWTTL-UHFFFAOYSA-N
assay
90%
impurities
10% 2-chlorobenzenesulfonyl chloride
refractive index
n20/D 1.559 (lit.)
bp
285 °C (lit.)
density
1.484 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Application
2-Chlorobenzenesulfonyl isocyanate may be used in the synthesis of N-thiazolyl-N′-(2-chlorobenzenesulfonyl)urea derivatives and N-(2-chlorophenylsulfonyl)-N′-(4-methoxy-6-methyl-triazin-2-yl)urea.
General description
2-Chlorobenzenesulfonyl isocyanate is an aryl isocyanate that can be synthesized by the catalytic carbonylation of potassium N,2- dichlorobenzenesulfonamidate in acetonitrile. The C-acylation of nitrogen bearing heterocycles using 2-chlorobenzenesulfonyl isocyanate has been reported.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Thiazolecarboxylic acid derivatives. 1. N-substituted 2-amino-4-methylthiazole-5-carboxylic acid derivatives.
Dovlatyan VV, et al.
Chemistry of Heterocyclic Compounds, 40(1), 84-89 (2004)
Catalytic carbonylation of potassium N,2-dichlorobenzenesulfonamidate to sulfonyl isocyanate.
Besenyei G, et al.
Reaction Kinetics and Catalysis Letters, 62(2), 321-326 (1997)
C-Acylation of Electron-Rich Heterocycles by o-Chlorobenzenesulfonyl Isocyanate.
Nam NL, et al.
ChemInform, 27(35) (1996)
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