479284
(R)-(-)-O-甲酰基扁桃酸酰氯
97%
别名:
(-)-O-甲酰-D-扁桃酰氯, (R)-(-)-α-(甲酰氧基)苯乙酰氯
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关于此项目
线性分子式:
HCO2CH(C6H5)COCl
化学文摘社编号:
分子量:
198.60
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
249-478-4
Beilstein/REAXYS Number:
5404068
MDL number:
Assay:
97%
InChI key
ZNLABNPTWSKGDX-MRVPVSSYSA-N
InChI
1S/C9H7ClO3/c10-9(12)8(13-6-11)7-4-2-1-3-5-7/h1-6,8H/t8-/m1/s1
SMILES string
ClC(=O)[C@H](OC=O)c1ccccc1
assay
97%
optical activity
[α]23/D −228°, neat
refractive index
n20/D 1.523 (lit.)
bp
221 °C (lit.)
density
1.275 g/mL at 25 °C (lit.)
functional group
acyl chloride, phenyl
storage temp.
2-8°C
Application
(R)-(−)-O-Formylmandeloyl chloride can be used as a chiral resolving agent for the resolution of spirobiindane.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Synthesis and application of a new hexamethyl-1, 1′-spirobiindane-based chiral bisphosphine (HMSI-PHOS) ligand in asymmetric allylic alkylation
Chang S, et al.
Organic & Biomolecular Chemistry, 16(13), 2239-2247 (2018)
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