480061
2,6-二甲基苯硼酸
≥95.0%
别名:
2,6-Dimethylbenzeneboronic acid, 2,6-Xyleneboronic acid, 2,6-Xylylboronic acid
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关于此项目
线性分子式:
(CH3)2C6H3B(OH)2
化学文摘社编号:
分子量:
149.98
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
方案
≥95.0%
杂质
<10% water
mp
105 °C (dec.) (lit.)
SMILES字符串
Cc1cccc(C)c1B(O)O
InChI
1S/C8H11BO2/c1-6-4-3-5-7(2)8(6)9(10)11/h3-5,10-11H,1-2H3
InChI key
ZXDTWWZIHJEZOG-UHFFFAOYSA-N
应用
Reagent used for
Reagent used in Prepration of
- Palladium catalyzed Suzuki-Miyaura coupling reactions
- One-pot ipso-nitration of arylboronic acids including broader substrate scope of heterocycles and functional groups
- Nickel-Catalyzed Cross-Coupling of Chromene Acetals and Boronic Acids
- Visible-light initiated aerobic oxidative hydroxylation catalyzed by Ru-complex
- Rhodium(I)-catalyzed 1,4-addition reactions
- Pd-catalyzed homocouplings
- Expanded scope of Cu assisted Suzuki-Miyaura coupling reactions including aryl chlorides and polyhalo aryl boronates
Reagent used in Prepration of
- Orally bioavialable G Protein-Coupled Receptor 40 agonists for diabetes treatment
- Solid phase synthesis and antitumor structure-activity relationship of Smac triazoloprolines and biarylalanines tetrapeptide libraries
- Protein Kinase inhibitors
其他说明
含不定量的酸酐
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Santos-Filho, E. F.; et al.
Tetrahedron Letters, 52, 5288-5288 (2011)
Sebastian T Le Quement et al.
ACS combinatorial science, 13(6), 667-675 (2011-09-13)
Apoptotic induction mechanisms are of crucial importance for the general homeostasis of multicellular organisms. In cancer the apoptotic pathways are downregulated, which, at least partly, is due to an abundance of inhibitors of apoptosis proteins (IAPs) that block the apoptotic
Rhodium(I)-catalyzed 1,4-addition of arylboronic acids to acrylic acid in water: one-step preparation of 3-arylpropionic acids
Vautravers, N. R.; Breit, B.
Synlett, 17, 2517-2520 (2011)
Room-temperature synthesis of tetra-ortho-substituted biaryls by NHC-catalyzed Suzuki-Miyaura couplings.
Linglin Wu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(46), 12886-12890 (2011-10-11)
Expanding the scope of the Cu assisted Suzuki-Miyaura reaction
Crowley, B. M.; et al.
Tetrahedron Letters, 52, 5055-5059 (2011)
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