480061
2,6-二甲基苯硼酸
≥95.0%
别名:
2,6-Dimethylbenzeneboronic acid, 2,6-Xyleneboronic acid, 2,6-Xylylboronic acid
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关于此项目
线性分子式:
(CH3)2C6H3B(OH)2
化学文摘社编号:
分子量:
149.98
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C8H11BO2/c1-6-4-3-5-7(2)8(6)9(10)11/h3-5,10-11H,1-2H3
SMILES string
Cc1cccc(C)c1B(O)O
InChI key
ZXDTWWZIHJEZOG-UHFFFAOYSA-N
assay
≥95.0%
impurities
<10% water
mp
105 °C (dec.) (lit.)
Quality Level
Application
Reagent used for
Reagent used in Prepration of
- Palladium catalyzed Suzuki-Miyaura coupling reactions
- One-pot ipso-nitration of arylboronic acids including broader substrate scope of heterocycles and functional groups
- Nickel-Catalyzed Cross-Coupling of Chromene Acetals and Boronic Acids
- Visible-light initiated aerobic oxidative hydroxylation catalyzed by Ru-complex
- Rhodium(I)-catalyzed 1,4-addition reactions
- Pd-catalyzed homocouplings
- Expanded scope of Cu assisted Suzuki-Miyaura coupling reactions including aryl chlorides and polyhalo aryl boronates
Reagent used in Prepration of
- Orally bioavialable G Protein-Coupled Receptor 40 agonists for diabetes treatment
- Solid phase synthesis and antitumor structure-activity relationship of Smac triazoloprolines and biarylalanines tetrapeptide libraries
- Protein Kinase inhibitors
Other Notes
含不定量的酸酐
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Sebastian T Le Quement et al.
ACS combinatorial science, 13(6), 667-675 (2011-09-13)
Apoptotic induction mechanisms are of crucial importance for the general homeostasis of multicellular organisms. In cancer the apoptotic pathways are downregulated, which, at least partly, is due to an abundance of inhibitors of apoptosis proteins (IAPs) that block the apoptotic
Thomas J A Graham et al.
Organic letters, 14(6), 1616-1619 (2012-03-06)
A modular and highly efficient protocol for the synthesis of 2-aryl- and heteroaryl-2H-chromenes is described. Under base-free conditions, readily accessible 2-ethoxy-2H-chromenes undergo C(sp(3))-O activation and C(sp(3))-C bond formation in the presence of an inexpensive nickel catalyst and boronic acids. This
Santos-Filho, E. F.; et al.
Tetrahedron Letters, 52, 5288-5288 (2011)
Rhodium(I)-catalyzed 1,4-addition of arylboronic acids to acrylic acid in water: one-step preparation of 3-arylpropionic acids
Vautravers, N. R.; Breit, B.
Synlett, 17, 2517-2520 (2011)
Room-temperature synthesis of tetra-ortho-substituted biaryls by NHC-catalyzed Suzuki-Miyaura couplings.
Linglin Wu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(46), 12886-12890 (2011-10-11)
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