480819
(R)-(+)-缩水甘油
97%, optical purity ee: 98% (GLC)
别名:
(R)-(+)-环氧乙烷-2-甲醇
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关于此项目
经验公式（希尔记法）:
C3H6O2
CAS Number:
分子量:
74.08
Beilstein:
79782
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
一般描述
Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.
应用
用于在 furanocembrane（一种海洋天然产物）的合成中构建环氧乙烯基碘化物中间体的手性结构单元。
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Self-react. C - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
储存分类代码
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 3
闪点(°F)
161.6 °F
闪点(°C)
72 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
A New Route for Protected Amino Alcohols from (R)-Glycidol. Copper (I) Mediated Alkylation of 4-Tosyloxymethyl-2-oxazolidinone.
Iwama S and Katsumura S.
Bulletin of the Chemical Society of Japan, 67(12), 3363-3365 (1994)
Tetrahedron Letters, 47, 6401-6401 (2006)
Synthesis of amino-1, 4-anhydro-d-pentitols and amino-1, 5-anhydro-d-hexitols with the arabino configuration from (R)-glycidol.
Aragones S, et al.
Tetrahedron Asymmetry, 14(13), 1847-1856 (2003)
Diastereoselective synthesis of ?-hydroxy-?-amino alcohols,(2S, 3S)-and (2S, 3R)-threoninol and-hydroxyphenylalaninol, from (R)-glycidol via the derived 4-hydroxymethyloxazolidinone.
Katsumura S, et al.
Tetrahedron Asymmetry, 5(2), 161-164 (1994)
Effect of imprinting sol-gel immobilized lipase with chiral template substrates in esterification of (R)-(+)-and (S)-(-)-glycidol.
Furukawa S, et al.
Journal of Molecular Catalysis. B, Enzymatic, 17(1), 23-28 (2002)
Chromatograms
suitable for GCsuitable for GCsuitable for GC我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
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