480819
(R)-(+)-缩水甘油
97%, optical purity ee: 98% (GLC)
别名:
(R)-(+)-环氧乙烷-2-甲醇
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关于此项目
经验公式（希尔记法）:
C3H6O2
化学文摘社编号:
分子量:
74.08
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
404-660-4
Beilstein/REAXYS Number:
79782
MDL number:
产品名称
(R)-(+)-缩水甘油, 97%, optical purity ee: 98% (GLC)
InChI key
CTKINSOISVBQLD-GSVOUGTGSA-N
InChI
1S/C3H6O2/c4-1-3-2-5-3/h3-4H,1-2H2/t3-/m1/s1
SMILES string
OC[C@@H]1CO1
assay
97%
optical activity
[α]23/D +15°, neat
optical purity
ee: 98% (GLC)
impurities
<3% dichloromethane
refractive index
n20/D 1.43 (lit.)
bp
56-57 °C/11 mmHg (lit.)
density
1.116 g/mL at 20 °C (lit.)
storage temp.
−20°C
Quality Level
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Application
用于在 furanocembrane（一种海洋天然产物）的合成中构建环氧乙烯基碘化物中间体的手性结构单元。
General description
Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Self-react. C - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
161.6 °F
flash_point_c
72 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Diastereoselective synthesis of ?-hydroxy-?-amino alcohols,(2S, 3S)-and (2S, 3R)-threoninol and-hydroxyphenylalaninol, from (R)-glycidol via the derived 4-hydroxymethyloxazolidinone.
Katsumura S, et al.
Tetrahedron Asymmetry, 5(2), 161-164 (1994)
Synthesis of amino-1, 4-anhydro-d-pentitols and amino-1, 5-anhydro-d-hexitols with the arabino configuration from (R)-glycidol.
Aragones S, et al.
Tetrahedron Asymmetry, 14(13), 1847-1856 (2003)
A New Route for Protected Amino Alcohols from (R)-Glycidol. Copper (I) Mediated Alkylation of 4-Tosyloxymethyl-2-oxazolidinone.
Iwama S and Katsumura S.
Bulletin of the Chemical Society of Japan, 67(12), 3363-3365 (1994)
Tetrahedron Letters, 47, 6401-6401 (2006)
Synthesis of propane-2, 3-diol combinatorial monomers.
Acevedo OL and Andrews RS.
Tetrahedron Letters, 37(23), 3931-3934 (1996)
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