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Merck
CN

483028

3,4-乙烯二氧噻吩

97%

别名:

2,3-二氢噻吩并[3,4-b]-1,4-二氧六环, EDOT

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关于此项目

经验公式(希尔记法):
C6H6O2S
化学文摘社编号:
分子量:
142.18
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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方案

97%

折射率

n20/D 1.5765 (lit.)

沸点

193 °C (lit.)

密度

1.331 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

C1COc2cscc2O1

InChI

1S/C6H6O2S/c1-2-8-6-4-9-3-5(6)7-1/h3-4H,1-2H2

InChI key

GKWLILHTTGWKLQ-UHFFFAOYSA-N

一般描述

3,4-乙二氧基噻吩(EDOT)是一种具有硫醇基的电活性导电单体,以供体-受体-供体的方式结合电子供体和电子受体。
单体可以用来合成导电聚合物。

应用

EDOT可以聚合形成聚(3,4-乙撑二氧噻吩)(PEDOT),用作基于电致变色聚合物(EC)的涂料,适于各种应用,如用于糖尿病监测的固态有机电化学超级电容器(OESC),电致变色器件(ECD)和碳纳米管(CNT)类电化学设备。
可用于:
  • 用作从HAuCl4 (254169)一锅法合成金纳米颗粒的还原剂。
  • 用作钯催化单芳基化和双芳基化反应的起始原料。
  • 合成有望用于光学应用的复合聚合物和共聚物。

象形图

Skull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

闪点(°F)

219.2 °F - closed cup

闪点(°C)

104 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Fei Li et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 6(20), 1901051-1901051 (2019-10-23)
The rapid development of microelectronics has equally rapidly increased the demand for miniaturized energy storage devices. On-chip microsupercapacitors (MSCs), as promising power candidates, possess great potential to complement or replace electrolytic capacitors and microbatteries in various applications. However, the areal
Zaid Aqrawe et al.
Polymers, 12(8) (2020-07-30)
The fabrication of stretchable conductive material through vapor phase polymerization of poly(3,4-ethylenedioxythiophene) (PEDOT) is presented alongside a method to easily pattern these materials with nanosecond laser structuring. The devices were constructed from sheets of vapor phase polymerized PEDOT doped with
Advanced Mat., 12, 481-494 (2000)
Hongmin Wang et al.
Nature communications, 11(1), 3882-3882 (2020-08-13)
Fired brick is a universal building material, produced by thousand-year-old technology, that throughout history has seldom served any other purpose. Here, we develop a scalable, cost-effective and versatile chemical synthesis using a fired brick to control oxidative radical polymerization and
Macromolecules, 37, 4087-4098 (2004)

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