493023
3-甲基-1-戊烯-4-炔-3-醇
98%
别名:
1-乙烯基-1-乙炔基乙醇
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
HC≡CC(CH3)(OH)CH=CH2
化学文摘社编号:
分子量:
96.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
221-770-6
MDL number:
产品名称
3-甲基-1-戊烯-4-炔-3-醇, 98%
InChI key
VBATUBQIYXCZPA-UHFFFAOYSA-N
InChI
1S/C6H8O/c1-4-6(3,7)5-2/h1,5,7H,2H2,3H3
SMILES string
CC(O)(C=C)C#C
assay
98%
refractive index
n20/D 1.446 (lit.)
bp
63-65 °C/100 mmHg (lit.)
density
0.89 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
正在寻找类似产品? 访问 产品对比指南
General description
3-Methyl-1-penten-4-yn-3-ol is an acetylenic alcohol. It reacts with ruthenium vinyl carbene to form a ten-membered η2-olefin coordinated ruthenacycle. The efficiency of different palladium catalysts for the hydrogenation of 3-methyl-1-penten-4-yn-3-ol under continuous-flow liquid-phase conditions has been evaluated. It undergoes allylic rearrangement to form cis and trans isomers of 3-methyl-2-penten-4-yn-l-ol.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
90.0 °F - closed cup
flash_point_c
32.2 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
From the Lindlar Catalyst to Supported Ligand-Modified Palladium Nanoparticles: Selectivity Patterns and Accessibility Constraints in the Continuous-Flow Three-Phase Hydrogenation of Acetylenic Compounds.
Vile G, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 20(20), 5926-5937 (2014)
Allyl rearrangement of 3-methyl-1-penten-4-yn-3-ol.
Skoda A, et al.
Chemical Papers, 43(6), 743-751 (1989)
1,2-Migration in the reactions of ruthenium vinyl carbene with propargyl alcohols.
Zhou X, et al.
Organic Chemistry Frontiers : An International Journal of Organic Chemistry / Royal Society of Chemistry, 1(9), 1077-1082 (2014)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持